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Physicochemical model as a method for calculating and making consistent thermodynamic properties of structural units in alkali silicate melts

  • Theoretical Inorganic Chemistry
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Abstract

The physicochemical modeling of formation of alkali silicate melts in the temperature range 298.15–1473 K has been performed. Correction of the results of calculations based on spectroscopic data has been performed to make consistent the thermodynamic properties of lithium, sodium, and potassium silicates and calculate the thermodynamic properties of structural units Qn, which exist in alkali silicate melts.

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Authors and Affiliations

  1. Institute of Mineralogy, Ural Branch, Russian Academy of Sciences, Miass, Chelyabinsk oblast, 456317, Russia

    O. N. Koroleva & M. V. Shtenberg

  2. Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1a, Irkutsk, 664033, Russia

    V. A. Bychinskii & A. A. Tupitsyn

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. A. Krenev & S. V. Fomichev

Authors
  1. O. N. Koroleva
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  2. V. A. Bychinskii
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  3. A. A. Tupitsyn
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  4. M. V. Shtenberg
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  5. V. A. Krenev
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  6. S. V. Fomichev
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Corresponding author

Correspondence to O. N. Koroleva.

Additional information

Original Russian Text © O.N. Koroleva, V.A. Bychinskii, A.A. Tupitsyn, M.V. Shtenberg, V.A. Krenev, S.V. Fomichev, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 9, pp. 1211–1217.

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Koroleva, O.N., Bychinskii, V.A., Tupitsyn, A.A. et al. Physicochemical model as a method for calculating and making consistent thermodynamic properties of structural units in alkali silicate melts. Russ. J. Inorg. Chem. 60, 1104–1109 (2015). https://doi.org/10.1134/S0036023615090107

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  • DOI: https://doi.org/10.1134/S0036023615090107

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