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Fe0.45S0.55-Ni0.66S0.34 section of the Fe-Ni-S phase diagram

  • Physicochemical Analysis of Inorganic Systems
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Abstract

The Fe0.45S0.55-Ni0.66S0.34 section of the Fe-Ni-S phase diagram was constructed using thermal analysis, microscopy, X-ray powder diffraction, and electron probe microanalysis data obtained for the samples prepared by isothermal annealing and thermal analysis and by directional solidification of Fe0.2665Ni0.2665S0.467 melt under quasi-equilibrium conditions. Four invariant phase reactions are found in this section. The solid-phase mechanism of pentlandite formation is verified.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    V. I. Kosyakov

  2. Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    E. F. Sinyakova

Authors
  1. V. I. Kosyakov
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  2. E. F. Sinyakova
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Original Russian Text © V.I. Kosyakov, E.F. Sinyakova, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 7, pp. 1212–1219.

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Kosyakov, V.I., Sinyakova, E.F. Fe0.45S0.55-Ni0.66S0.34 section of the Fe-Ni-S phase diagram. Russ. J. Inorg. Chem. 54, 1151–1158 (2009). https://doi.org/10.1134/S0036023609070250

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  • DOI: https://doi.org/10.1134/S0036023609070250

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