Skip to main content
Log in

A study of structural and molecular weight characteristics of poly(aluminum hydroxychloride) nanoparticles by small-angle X-ray scattering and sedimentation analysis

  • Experiment
  • Published:
Nanotechnologies in Russia Aims and scope Submit manuscript

Abstract

It has been established by small-angle X-ray scattering and sedimentation analysis that aqueous solutions of poly(aluminum hydroxychloride) are disperse systems comprising two types of nanoparticles considerably different in size. The volume content, molecular weights, radii of gyration, characteristic size, specific surface, fractal dimensions, and shape of poly(aluminum hydroxychloride) nanoparticles have been determined. The particles of poly(aluminum hydroxychloride) have been shown to be rather stable entities, and the addition of HCl has practically no effect on their molecular weight or structural characteristics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E. S. Lukin, “Modern High-Density Oxide Ceramic Materials with a Controlled Microstructure,” Ogneupory Tekh. Keram., No. 4, 2–13 (1996).

  2. O. E. Litmanovich, G. V. Marmuzov, A. A. Litmanovich, and I. M. Papisov, “Selectivity of the Interactions between Copper Nanoparticles and Macromolecules of Polyelectrolyte and Nonionogenic Polymers,” Vysokomol. Soedin., Ser. A 45(9), 1533–1543 (2003) [Polym. Sci., Ser. A 45 (9), 906–916 (2003)].

    CAS  Google Scholar 

  3. S. A. Ozerin, S. A. Zav’yalov, and S. N. Chvalun, “Synthesis, Structure, and Properties of Metal-Polymer Nanocomposites Based on Silver and Poly-p-Xylylene,” Vysokomol. Soedin., Ser. A 41(11), 1993–1999 (2001) [Polym. Sci., Ser. A 41 (11), 1171–1176 (2001)].

    Google Scholar 

  4. S. S. Ivanchev, A. M. Mesh, N. Reichelt, S. Ya. Khaikin, A. Hesse, and S. V. Myakin, “Preparation of Nanocomposites by Alkoxysilane Hydrolysis in a Polypropylene Matrix,” Vysokomol. Soedin., Ser. A 44(6), 996–1001 (2002) [Polym. Sci., Ser. A 44 (6), 623–627 (2002)].

    CAS  Google Scholar 

  5. I. A. Novakov, F. S. Radchenko, and I. M. Papisov, “Formation of Polycomplexes Based on Polyacrylamide and Aluminum Salts,” Vysokomol. Soedin., Ser. A 45(8), 1340–1349 (2003) [Polym. Sci., Ser. A 45 (8), 805–808 (2003)].

    CAS  Google Scholar 

  6. I. A. Novakov, F. S. Radchenko, A. S. Pastukhov, and I. M. Papisov, “The Properties of Aqueous Solutions of Polymer-Colloid Complexes of Polyacrylamide with Poly(aluminum hydroxychloride),” Vysokomol. Soedin., Ser. A 47(1), 73–80 (2005) [Polym. Sci., Ser. A 47 (1), 57–60 (2005)].

    CAS  Google Scholar 

  7. A. V. Volkov, M. A. Moskvina, A. B. Zezin, A. L. Volynksii, and N. F. Bakeev, “The Effect of a Polymer Matrix on the Structure of Nanocompositions Containing Cadmium Sulfide,” Vysokomol. Soedin., Ser. A 45(2), 283–291 (2003) [Polym. Sci., Ser. A 45 (2), 166–173 (2003)].

    CAS  Google Scholar 

  8. C. Y. Brinker and G. W. Scherer, Sol-Gel Science: the Physics and Chemistry of Sol-Gel Processing (Academic, Boston, 1990).

    Google Scholar 

  9. O. A. Shilova and V. V. Shilov, “Nanocomposite Oxide and Hybride Organic-Inorganic Materials Obtained by the Sol-Gel Method: Synthesis, Properties, and Applications,” Nanosyst., Nanomater., Nanotechnol. 1(1), 9–83 (2003).

    CAS  Google Scholar 

  10. G. G. Kagramanov, P. V. Kholkin, and E. A. Lukashov, “Simulation of the Sol-Gel Process of the Formation of Selective Layers of Ceramic Membranes,” Ogneupory Keram., No. 5, 2–13 (2001).

  11. A. R. Barron and S. J. Obrey, “Supra-Molecular Alumoxanes,” US Patent No. 6322890 (November 27, 2001).

  12. O. B. Pavlova-Verevkina, V. F. Kargin, and Yu. E. Roginskaya, “Preparation and Properties of Stable Aluminum Hydroxide Sols: Morphology of Highly Dispersed Aluminum Hydroxide (Pseudoboehmite),” Kolloidn. Zh. 55(3), 127–137 (1993).

    CAS  Google Scholar 

  13. V. V. Nazarov, E. K. Valesyan, and N. G. Medvedkova, “The Effect of Electrolytes on the Aggregation Stability of Boehmite Hydrosols,” Kolloidn. Zh. 61(1), 91–94 (1999) [Colloid J. 61 (1), 82–85 (1999)].

    Google Scholar 

  14. M. A. Fedotov, O. P. Krivoruchko, and R. A. Buyanov, “Interaction of Initial Anionic Salts with Products of Hydrolytic Polymerization of Aqua Ions,” Izv. Akad. Nauk SSSR, Ser. Khim., No. 10, 2183–2186 (1977).

  15. O. P. Krivoruchko and R. A. Buyanov, Thermodynamics and Structure of Hydroxocomplexes in Solutions (Nauka, Leningrad, 1980) [in Russian].

    Google Scholar 

  16. M. G. Osmolovskii, I. A. Zvereva, and D. I. Tarasenko, “An Uncharged Cluster-the Main Structural Element of Amorphous Hydroxides,” in Proceedings of the Sixth All-Russia (International) Conference “Physicochemistry of Ultradispersed (Nano-) Systems,” Moscow Institute of Engineering Physics (MIFI), Moscow, Russia, 2003 (Moscow, 2003).

  17. M. E. Shishniashvili, V. A. Kargin, and A. L. Batsanadze, “Preparation of Aluminum Hydroxy Salts and Investigation of Their Properties,” Zh. Fiz. Khim. 21(3), 391–396 (1947).

    CAS  Google Scholar 

  18. E. A. Levitskii and V. N. Maksimov, “On the Composition of Products of Hydrolysis in Solutions of Aluminum Chloride,” Dokl. Akad. Nauk SSSR 141(4), 865–868 (1961).

    CAS  Google Scholar 

  19. I. M. Solomentseva, N. G. Gerasimenko, and V. V. Teselkin, “Size and Density Characteristics for Products of Hydrolysis of Aluminum Hydroxychlorides,” Khim. Tekhnol. Vody 15(11–12), 719–725 (1993).

    CAS  Google Scholar 

  20. O. S. Zakharchenko, E. A. Litmanovich, F. S. Radchenko, A. S. Pastukhov, A. B. Zezin, I. A. Novakov, and V. A. Kabanov, “Photon Correlation Spectroscopic Study of the Aggregative Stability of Colloidal Particles of Aluminum Pentahydroxide Chloride,” Kolloidn. Zh. 68(4), 467–471 (2006) [Colloid J. 68 (4), 425–429 (2006)].

    Google Scholar 

  21. O. P. Krivoruchko, V. N. Kolomiichuk, and R. A. Buyanov, “Investigation of the Formation of Aluminum(III) Hydroxides Using the Small-Angle X-Ray Scattering Method,” Zh. Neorg. Khim. 30(2), 306–310 (1985).

    CAS  Google Scholar 

  22. I. A. Novakov, N. U. Bykadorov, S. S Radchenko, Yu. N. Kargin, V. F. Mokhov, O. K. Zhokhova, A. I. Parkhomenko, and P. I. Otchenashev, RF Patent No. 2083495, Byull. Izobret., No. 19 (July 10, 1997).

  23. D. I. Svergun, “Determination of the Regularization Parameter in Indirect-Transform Methods Using Perceptual Criteria,” J. Appl. Crystallogr. 25, 495–503 (1992).

    Article  Google Scholar 

  24. D. I. Svergun and L. A. Feigin, Structure Analysis by Small-Angle X-Ray and Neutron Scattering (Nauka, Moscow, 1986; Plenum, New York, 1987).

    Google Scholar 

  25. A. Guinier, “New Method for the Small-Angle Scattering Data,” Ann. Phys. (Paris) 12, 161–237 (1939).

    CAS  Google Scholar 

  26. D. I. Svergun, “Restoring Low-Resolution Structure of Biological Macromolecules from Solution Scattering Using Simulated Annealing,” Biophys. J. 76(6), 2879–2886 (1999).

    Article  PubMed  CAS  Google Scholar 

  27. V. V. Volkov and D. I. Svergun, “Uniqueness of Ab Initio Shape Determination in Small-Angle Scattering,” J. Appl. Crystallogr. 36 Part 3 (1), 860–864 (2003).

    Article  CAS  Google Scholar 

  28. A. N. Ozerin, A. M. Muzafarov, A. I. Kuklin, A. Kh. Islamov, V. I. Gordelyi, G. M. Ignat’eva, V. D. Myakushev, L. A. Ozerina, and E. A. Tatarinova, “Determination of the Shape of Dendrimer Macromolecules in Solutions from Small-Angle Neutron Scattering Data,” Dokl. Akad. Nauk, Ser. Khim. 395(4), 487–490 (2004) [Dokl. Chem. 395 (Part 2), 59–62 (2004)].

    Google Scholar 

  29. A. N. Ozerin, D. I. Svergun, V. V. Volkov, A. I. Kuklin, V. I. Gordelyi, A. Kh. Islamov, L. A. Ozerina, and D. S. Zavorotnyuk, “The Spatial Structure of Dendritic Macromolecules,” J. Appl. Crystallogr. 38, 996–1003 (2005).

    Article  CAS  Google Scholar 

  30. A. N. Ozerin, A. M. Muzafarov, L. A. Ozerina, D. S. Zavorotnyuk, I. B. Meshkov, O. B. Pavlova-Verevkina, and M. A. Beshenko, “Reproduction of the Shape of Nanodisperse Particles from Small-Angle X-Ray Scattering Data without Use of a Priori Information,” Dokl. Akad. Nauk 411(1), 71–74 (2006) [Dokl. Chem. 411 (Part 1), 202–205 (2006)].

    Google Scholar 

  31. M. B. Kozin and D. I. Svergun, “Automated Matching of High- and Low-Resolution Structural Models,” J. Appl. Crystallogr. 34, 33–41 (2001).

    Article  CAS  Google Scholar 

  32. P. V. Konarev, M. V. Petoukhov, and D. I. Svergun, “MASSHA-A Graphics System for Rigid-Body Modelling of Macromolecular Complexes against Solution Scattering Data,” J. Appl. Crystallogr. 34, 527–532 (2001).

    Article  CAS  Google Scholar 

  33. J. E. Martin and A. J. Hurd, “Scattering from Fractals,” J. Appl. Crystallogr. 20, 61–78 (1987).

    Article  CAS  Google Scholar 

  34. G. Porod, “The X-Ray Small-Angle Scattering of Close-Packed Colloid Systems,” Kolloid. Z. 125, 109–122 (1952).

    Google Scholar 

  35. G. Beaucage, “Approximations Leading to a Unified Exponential/Power-Law Approach to Small-Angle Scattering,” J. Appl. Crystallogr. 28, 717–728 (1995).

    Article  CAS  Google Scholar 

  36. G. Beaucage, “Small-Angle Scattering from Polymeric Mass Fractals of Arbitrary Mass-Fractal Dimension,” J. Appl. Crystallogr. 29, 134–146 (1996).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to F. S. Radchenko.

Additional information

Original Russian Text © A.S. Ozerin, F.S. Radchenko, G.I. Timofeeva, I.A. Novakov, 2009, published in Rossiiskie nanotekhnologii, 2009, Vol. 4, Nos. 1–2.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ozerin, A.S., Radchenko, F.S., Timofeeva, G.I. et al. A study of structural and molecular weight characteristics of poly(aluminum hydroxychloride) nanoparticles by small-angle X-ray scattering and sedimentation analysis. Nanotechnol Russia 4, 93–101 (2009). https://doi.org/10.1134/S1995078009010108

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1995078009010108

Keywords

Navigation