Since the isolation of a Mg–Mg complex, research on low-oxidation-state s-block chemistry has flourished. An approach to forming metal–metal bonds between Mg and the heavier alkaline earth metals (Ca, Sr and Ba) is now demonstrated. The unusual electronic nature of these compounds could stimulate further discussions of metal–metal bonding.
References
Green, S. P., Jones, C. & Stasch, A. Stable magnesium(I) compounds with Mg–Mg bonds. Science 318, 1754–1757 (2007). This paper reports the isolation of a MgI complex with a unique Mg–Mg bond.
Jones, C. Dimeric magnesium(i) β-diketiminates: a new class of quasi-universal reducing agent. Nat. Rev. Chem. 1, 0059 (2017). A review article that presents applications of Mg–Mg complexes as mild reducing agents.
Rösch, B. et al. Dinitrogen complexation and reduction at low-valent calcium. Science 371, 1125–1128 (2021). This paper reports N2 activation with a Ca complex.
Mai, J., Rösch, B., Patel, N., Langer, J. & Harder, S. On the existence of low-valent magnesium calcium complexes. Chem. Science 14, 4724–4734 (2023). This paper reports attempts to make a Mg–Ca bond.
Rösch, B. et al. Strong reducing magnesium(0) complexes. Nature 592, 717–721 (2021). This paper reports the synthesis, structure and reactivity of a complex with unusual Mg–Na bonding.
Mulvey, R. E. Modern ate chemistry: applications of synergic mixed alkali metal−magnesium or −zinc reagents in synthesis and structure building. Organometallics 25, 1060–1075 (2006). A review article that highlights the applications of two cooperating metals, which show extreme reactivity and surprisingly selective deprotonation reactions.
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This is a summary of: Mai, J. et al. Heterobimetallic alkaline earth metal–metal bonding. Nat. Synth. https://doi.org/10.1038/s44160-023-00451-y (2023).
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Achieving unusual metal–metal bonding in the s-block. Nat. Synth 3, 299–300 (2024). https://doi.org/10.1038/s44160-023-00452-x
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DOI: https://doi.org/10.1038/s44160-023-00452-x
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