Metalloclusters play important roles in biology, materials and catalysis; however, their synthesis is not straightforward. Now, a strategy is reported where a controlled level of substitution based on incoming ligand steric properties is achieved, creating interesting metallocluster compositions.
References
Cesari, C., Shon, J.-H., Zacchini, S. & Berben, L. A. Chem. Soc. Rev. 50, 9503–9539 (2021).
Muetterties, E. L. Bull. Soc. Chim. Belg. 84, 959–986 (1975).
Bostelaar, T. M., Brown, A. C., Sridharan, A. & Suess, D. L. M. Nat. Synth. https://doi.org/10.1038/s44160-023-00286-7 (2023).
Huang, J., Schanz, H.-J., Stevens, E. D. & Nolan, S. P. Organometallics 18, 2370–2375 (1999).
Arduengo, A. J. III, Harlow, R. L. & Kline, M. J. Am. Chem. Soc. 113, 361–363 (1991).
Huang, J. & Nolan, S. P. J. Am. Chem. Soc. 121, 9889–9890 (1999).
Weskamp, T., Schattenmann, W. C., Spiegler, M. & Herrmann, W. A. Angew. Chem. Int. Ed. 37, 2490–2493 (1998).
Huang, J., Stevens, E. D., Nolan, S. P. & Petersen, J. L. J. Am. Chem. Soc. 121, 2674–2678 (1999).
Fortman, G. C. & Nolan, S. P. Chem. Soc. Rev. 40, 5151–5169 (2011).
Crudden, C. M. et al. Nat. Chem. 6, 409–414 (2014).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Competing interests
The author declares no competing interests.
Rights and permissions
About this article
Cite this article
Nolan, S.P. Controlled cluster compositions. Nat. Synth 2, 701–702 (2023). https://doi.org/10.1038/s44160-023-00282-x
Published:
Issue Date:
DOI: https://doi.org/10.1038/s44160-023-00282-x
- Springer Nature Limited