Indirect methods are generally adopted to elucidate complicated mechanisms of transition metal catalysis. Now, a way to directly observe transient manganese species and monitor key reaction steps has been established by using time-resolved multiple-probe spectroscopy.
References
Hammarback, L. A. et al. Nat. Catal. https://doi.org/10.1038/s41929-018-0145-y (2018).
Valyaev, D. A., Lavigne, G. & Lugan, N. Coord. Chem. Rev. 308, 191–235 (2016).
Zhou, B., Chen, H. & Wang, C. J. Am. Chem. Soc. 135, 1264–1267 (2013).
Yahaya, N. P. et al. Angew. Chem. Int. Ed. 55, 12455–12459 (2016).
Zhou, B., Ma, P., Chen, H. & Wang, C. Chem. Commun. 50, 14558–14561 (2014).
Liu, W., Bang, J., Zhang, Y. & Ackermann, L. Angew. Chem. Int. Ed. 54, 14137–14140 (2015).
Kuninobu, Y., Nishina, Y., Takeuchi, T. & Takai, K. Angew. Chem. Int. Ed. 46, 6518–6520 (2007).
Zhou, B., Hu, Y. & Wang, C. Angew. Chem. Int. Ed. 54, 13659–13663 (2015).
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Wang, C. Light up the dark paths. Nat Catal 1, 816–817 (2018). https://doi.org/10.1038/s41929-018-0180-8
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DOI: https://doi.org/10.1038/s41929-018-0180-8
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