Skip to main content
Log in

Reply to: On the ferroelectricity of CH3NH3PbI3 perovskites

  • Matters Arising
  • Published:

From Nature Materials

View current issue Submit your manuscript

A Publisher Correction to this article was published on 30 September 2019

The Original Article was published on 16 September 2019

This article has been updated

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1: Studies of CH3NH3PbI3 thin films with different crystallographic orientation.
Fig. 2: DART-PFM and LDV-PFM measurements of the original sample in our Article.

Change history

  • 30 September 2019

    An amendment to this paper has been published and can be accessed via a link at the top of the paper.

References

  1. Schulz, A. D. et al. On the ferroelectricity of CH3NH3PbI3 perovskites. Nat. Mater. https://doi.org/10.1038/s41563-019-0480-7 (2019).

  2. Liu, Y. et al. Chemical nature of ferroelastic twin domains in CH3NH3PbI3 perovskite. Nat. Mater. 17, 1013–1019 (2018).

    Article  CAS  Google Scholar 

  3. Gruverman, A., Auciello, O. & Tokumoto, H. Scanning force microscopy for the study of domain structure in ferroelectric thin films. J. Vac. Sci. Technol. B 14, 602–605 (1996).

    Article  Google Scholar 

  4. Jesse, S., Baddorf, A. P. & Kalinin, S. V. Dynamic behaviour in piezoresponse force microscopy. Nanotechnology 17, 1615–1628 (2006).

    Article  CAS  Google Scholar 

  5. Eliseev, E. A. et al. Electrostrictive and electrostatic responses in contact mode voltage modulated scanning probe microscopies. Appl. Phys. Lett. 104, 232901 (2014).

    Article  Google Scholar 

  6. Collins, L., Liu, Y., Ovchinnikova, O. S. & Proksch, R. Quantitative electromechanical atomic force microscopy. ACS Nano 13, 8055–8066 (2019).

    Article  CAS  Google Scholar 

  7. Balke, N. et al. Differentiating ferroelectric and nonferroelectric electromechanical effects with scanning probe microscopy. ACS Nano 9, 6484–6492 (2015).

    Article  CAS  Google Scholar 

  8. Vasudevan, R. K., Balke, N., Maksymovych, P., Jesse, S. & Kalinin, S. V. Ferroelectric or non-ferroelectric: why so many materials exhibit “ferroelectricity” on the nanoscale. Appl. Phys. Rev. 4, 021302 (2017).

    Article  Google Scholar 

  9. Catalan, G., Scott, J., Schilling, A. & Gregg, J. Universality of the scaling law for ferroic domains. Preprint at https://arxiv.org/abs/cond-mat/0608338 (2006).

  10. Vorpahl, S. M. et al. Orientation of ferroelectric domains and disappearance upon heating methylammonium lead triiodide perovskite from tetragonal to cubic phase. ACS Appl. Energy Mater. 1, 1534–1539 (2018).

    Article  CAS  Google Scholar 

  11. Gomez, A., Wang, Q., Goni, A. R., Campoy-Quiles, M. & Abate, A. Ferroelectricity-free lead halide perovskites. Energy Environ. Sci. 12, 2537–2547 (2019).

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This research was conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility.

Author information

Authors and Affiliations

Authors

Contributions

Y.L. prepared the samples. Y.L. and R.P. performed experiments. Y.L., A.V.I., R.P., L.C., S.J., S.V.K. and O.S.O. wrote the manuscript. All authors contributed to discussions.

Corresponding author

Correspondence to Olga S. Ovchinnikova.

Ethics declarations

Competing interests

The authors declare no competing interests.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, Y., Collins, L., Proksch, R. et al. Reply to: On the ferroelectricity of CH3NH3PbI3 perovskites. Nat. Mater. 18, 1051–1053 (2019). https://doi.org/10.1038/s41563-019-0481-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/s41563-019-0481-6

  • Springer Nature Limited

Navigation