Bipolar membranes are emerging as an enabling component in numerous energy-relevant electrochemical devices, but a greater understanding of how they operate in complex electrolytes is needed. Research now reveals that ionic species in mixed-ion electrolytes can block the heart of the membrane, the bipolar junction, hampering its performance.
References
Oener, S. Z., Foster, M. J. & Boettcher, S. W. Science 369, 1099–1103 (2020).
Seeberger, D., McLaughlin, D., Hauenstein, P. & Thiele, S. Sustain. Energy Fuels 4, 2508–2518 (2020).
Vermaas, D. A. & Smith, W. A. ACS Energy Lett. 1, 1143–1148 (2016).
Toh, W. L., Dinh, H. Q., Chu, An, T., Sauvé, E. R. & Surendranath, Y. Nat. Energy https://doi.org/10.1038/s41560-023-01404-7 (2023).
Disch, J., Ingenhoven, S. & Vierrath, S. Adv. Energy Mater. 13, 2301614 (2023).
Monteiro, M. C. O., Philips, M. F., Schouten, K. J. P. & Koper, M. T. M. Nat. Commun. 12, 4943 (2021).
Chen, L., Xu, Q. & Boettcher, S. W. Joule 7, 1867–1886 (2023).
Oener, S. Z., Twight, L. P., Lindquist, G. A. & Boettcher, S. W. ACS Energy Lett. https://doi.org/10.1021/acsenergylett.0c02078 (2021).
Lucas, É. et al. Preprint at ChemRxiv https://doi.org/10.26434/chemrxiv-2023-n4c6x (2023).
Luo, T., Abdu, S. & Wessling, M. J. Memb. Sci. 555, 429–454 (2018).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Competing interests
The author declares no competing interests.
Rights and permissions
About this article
Cite this article
Oener, S.Z. Ions block up the junction. Nat Energy 8, 1313–1314 (2023). https://doi.org/10.1038/s41560-023-01410-9
Published:
Issue Date:
DOI: https://doi.org/10.1038/s41560-023-01410-9
- Springer Nature Limited