Skip to main content
Log in

Mechanochemistry

How polymers dance to the pulses of ultrasound

  • News & Views
  • Published:

From Nature Chemistry

View current issue Submit your manuscript

Scientists have been studying how polymers break in solutions for decades, but the mechanism by which chains are stretched to the point of covalent bond scission is not trivial. Now, an experiment series provides ample support for a dynamic model in which chains uncoil from end to middle, while concurrently relaxing.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1: Previous and new models for solvodynamic shear-induced polymer mechanochemistry.

References

  1. May, P. A. & Moore, J. S. Chem. Soc. Rev. 42, 7497–7506 (2013).

    Article  CAS  PubMed  Google Scholar 

  2. Lockett, F. J. Nature 222, 937–939 (1969).

    Article  Google Scholar 

  3. Aharonovich, S. & Diesendruck, C. E. React. Funct. Polym. 131, 237–242 (2018).

    Article  CAS  Google Scholar 

  4. Garcia-Manyes, S. & Beedle, A. E. M. Nat. Rev. Chem. 1, 0083 (2017).

    Article  CAS  Google Scholar 

  5. Klok, H.-A., Herrmann, A. & Göstl, R. ACS Polym. Au 2, 208–212 (2022).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  6. O’Neill, R. T. & Boulatov, R. Nat. Chem. https://doi.org/10.1038/s41557-023-01266-2 (2023).

    Article  PubMed  Google Scholar 

  7. Lloyd, E. M., Vakil, J. R., Yao, Y., Sottos, N. R. & Craig, S. L. J. Am. Chem. Soc. 145, 751–768 (2023).

    Article  CAS  PubMed  Google Scholar 

  8. Zhang, H., Lin, Y., Xu, Y. & Weng, W. in Polymer Mechanochemistry Vol. 369 (ed. Boulatov, R.) 135–207 (Springer, 2015).

  9. Zhang, H. & Diesendruck, C. E. Angew. Chem. Int. Ed. 62, e202213980 (2023).

    Article  CAS  Google Scholar 

  10. Lenhardt, J. M., Black Ramirez, A. L., Lee, B., Kouznetsova, T. B. & Craig, S. L. Macromolecules 48, 6396–6403 (2015).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Charles E. Diesendruck.

Ethics declarations

Competing interests

The author declares no competing interests.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Diesendruck, C.E. How polymers dance to the pulses of ultrasound. Nat. Chem. 15, 1199–1201 (2023). https://doi.org/10.1038/s41557-023-01299-7

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/s41557-023-01299-7

  • Springer Nature Limited

Navigation