Although Li–O2 batteries offer high theoretical energy storage capacities, few approach these limits. Now, a class of redox mediators is shown to send the discharge reaction from the electrode surface into the electrolyte solution, boosting device capacities and providing selection criteria for future efforts.
References
Armand, M. & Tarascon, J.-M. Nature 451, 652–657 (2008).
Bruce, P. G., Freunberger, S. A., Hardwick, L. J. & Tarascon, J.-M. Nat. Mater. 11, 19–29 (2012).
Askins, E. J. et al. Nat. Chem. https://doi.org/10.1038/s41557-023-01268-0 (2023).
Aurbach, D., McCloskey, B. D., Nazar, L. F. & Bruce, P. G. Nat. Energy 1, 16128 (2016).
Kwak, W.-J. et al. Chem. Rev. 120, 6626–6683 (2020).
Zhang, X. et al. J. Phys. Chem. Lett. 8, 2334–2338 (2017).
Mahne, N. et al. Nat. Energy 2, 17036 (2017).
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Peng, Z. Li–O2 battery redox mediators go positive. Nat. Chem. 15, 1206–1208 (2023). https://doi.org/10.1038/s41557-023-01296-w
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DOI: https://doi.org/10.1038/s41557-023-01296-w
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