Abstract
It has been a great challenge to achieve the direct light manipulation of matter on a bulk scale. In this work the direct light propulsion of matter is observed on a macroscopic scale using a bulk graphene-based material. The unique structure and properties of graphene, and the novel morphology of the bulk three-dimensional linked graphene material make it capable not only of absorbing light at various wavelengths but also of emitting energetic electrons efficiently enough to drive the bulk material, following Newtonian mechanics. Thus, the unique photonic and electronic properties of individual graphene sheets are manifested in the response of the bulk state. These results offer an exciting opportunity to bring about bulk-scale light manipulation with the potential to realize long-sought applications in areas such as the solar sail and space transportation driven directly by sunlight.
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References
Ashkin, A. Acceleration and trapping of particles by radiation pressure. Phys. Rev. Lett. 24, 156–159 (1970).
Grier, D. G. A revolution in optical manipulation. Nature 424, 810–816 (2003).
Swartzlander, G. A., Peterson, T. J., Artusio-Glimpse, A. B. & Raisanen, A. D. Stable optical lift. Nature Photon. 5, 48–51 (2011).
Dogariu, A., Sukhov, S. & Saenz, J. J. Optically induced ‘negative forces’. Nature Photon. 7, 24–27 (2013).
Kane, B. Levitated spinning graphene flakes in an electric quadrupole ion trap. Phys. Rev. B 82, 115441 (2010).
Marago, O. M. et al. Brownian motion of graphene. ACS Nano 4, 7515–7523 (2010).
Twombly, C. W., Evans, J. S. & Smalyukh, I. I. Optical manipulation of self-aligned graphene flakes in liquid crystals. Opt. Express 21, 1324–1334 (2013).
Ashkin, A. History of optical trapping and manipulation of small-neutral particle, atoms, and molecules. IEEE J. Sel. Top. Quantum Electron. 6, 841–856 (2000).
Shvedov, V. G. et al. Giant optical manipulation. Phys. Rev. Lett. 105, 118103 (2010).
Shvedov, V. G., Hnatovsky, C., Rode, A. V. & Krolikowski, W. Robust trapping and manipulation of airborne particles with a bottle beam. Opt. Express 19, 17350–17356 (2011).
Kobayashi, M. & Abe, J. Optical motion control of maglev graphite. J. Am. Chem. Soc. 134, 20593–20596 (2012).
Ageev, V. P. et al. Experimental and theoretical modeling of laser propulsion. Acta Astronaut. 7, 79–90 (1980).
Phipps, C. et al. Review: laser-ablation propulsion. J. Propul. Power 26, 609–637 (2010).
Tsu, T. C. Interplanetary travel by solar sail. ARS J. 29, 422–427 (1959).
Tsuda, Y. et al. Flight status of IKAROS deep space solar sail demonstrator. Acta Astronaut. 69, 833–840 (2011).
Nair, R. R. et al. Fine structure constant defines visual transparency of graphene. Science 320, 1308 (2008).
Patil, V., Capone, A., Strauf, S. & Yang, E. H. Improved photoresponse with enhanced photoelectric contribution in fully suspended graphene photodetectors. Sci. Rep. 3, 2791 (2013).
Li, T. et al. Femtosecond population inversion and stimulated emission of dense Dirac fermions in graphene. Phys. Rev. Lett. 108, 167401 (2012).
Perakis, I. E. Stimulated near-infrared light emission in graphene. Physics 5, 43 (2012).
Strait, J. H. et al. Very slow cooling dynamics of photoexcited carriers in graphene observed by optical-pump terahertz-probe spectroscopy. Nano Lett. 11, 4902–4906 (2011).
Wu, Y. et al. Three-dimensionally bonded spongy graphene material with super compressive elasticity and near-zero Poisson's ratio. Nature Commun. 6, 6141 (2015).
Xu, Y., Sheng, K., Li, C. & Shi, G. Self-assembled graphene hydrogel via a one-step hydrothermal process. ACS Nano 4, 4324–4330 (2010).
Zhou, Y., Bao, Q., Tang, L. A. L., Zhong, Y. & Loh, K. P. Hydrothermal dehydration for the ‘green’ reduction of exfoliated graphene oxide to graphene and demonstration of tunable optical limiting properties. Chem. Mater. 21, 2950–2956 (2009).
Wehling, T. O., Katsnelson, M. I. & Lichtenstein, A. I. Impurities on graphene: midgap states and migration barriers. Phys. Rev. B 80, 085428 (2009).
Wu, X. et al. Epitaxial-graphene/graphene-oxide junction: an essential step towards epitaxial graphene electronics. Phys. Rev. Lett. 101, 026801 (2008).
Loh, K. P., Bao, Q. L., Eda, G. & Chhowalla, M. Graphene oxide as a chemically tunable platform for optical applications. Nature Chem. 2, 1015–1024 (2010).
Meyer, J. C. et al. The structure of suspended graphene sheets. Nature 446, 60–63 (2007).
Prechtel, L. et al. Time-resolved ultrafast photocurrents and terahertz generation in freely suspended graphene. Nature Commun. 3, 646 (2012).
Kim, J. et al. Unconventional terahertz carrier relaxation in graphene oxide: observation of enhanced Auger recombination due to defect saturation. ACS Nano 8, 2486–2494 (2014).
Eda, G., Mattevi, C., Yamaguchi, H., Kim, H. & Chhowalla, M. Insulator to semimetal transition in graphene oxide. J. Phys. Chem. C 113, 15768–15771 (2009).
Campos-Delgado, J. et al. Thermal stability studies of CVD-grown graphene nanoribbons: defect annealing and loop formation. Chem. Phys. Lett. 469, 177–182 (2009).
Winzer, T., Knorr, A. & Malic, E. Carrier multiplication in graphene. Nano Lett. 10, 4839–4843 (2010).
Winzer, T. & Malic, E. Impact of Auger processes on carrier dynamics in graphene. Phys. Rev. B 85, 241404 (2012).
Winzer, T., Malic, E. & Knorr, A. Microscopic mechanism for transient population inversion and optical gain in graphene. Phys. Rev. B 87, 165413 (2013).
Brida, D. et al. Ultrafast collinear scattering and carrier multiplication in graphene. Nature Commun. 4, 1987 (2013).
Gabor, N. M. Impact excitation and electron–hole multiplication in graphene and carbon nanotubes. Acc. Chem. Res. 46, 1348–1357 (2013).
Gabor, N. M. et al. Hot carrier-assisted intrinsic photoresponse in graphene. Science 334, 648–652 (2011).
Tielrooij, K. J. et al. Photoexcitation cascade and multiple hot-carrier generation in graphene. Nature Phys. 9, 248–252 (2013).
Dushman, S. Electron emission from metals as a function of temperature. Phys. Rev. 21, 623–636 (1923).
Turner, L. W. (ed) Electronics Engineer’s Reference Book 4th edn (Newnes-Butterworth, 1976).
Yaghoobi, P., Moghaddam, M. V. & Nojeh, A. ‘Heat trap’: light-induced localized heating and thermionic electron emission from carbon nanotube arrays. Solid State Commun. 151, 1105–1108 (2011).
Oida, S., Hannon, J. B., Tromp, R. M., McFeely, F. R. & Yurkas, J. A simple in situ method to detect graphene formation at SiC surfaces. Appl. Phys. Lett. 98, 213106 (2011).
Malko, D., Neiss, C., Vines, F. & Gorling, A. Competition for graphene: graphynes with direction-dependent Dirac cones. Phys. Rev. Lett. 108, 086804 (2012).
Vogt, P. et al. Silicene: compelling experimental evidence for graphenelike two-dimensional silicon. Phys. Rev. Lett. 108, 155501 (2012).
Cahangirov, S., Topsakal, M., Akturk, E., Sahin, H. & Ciraci, S. Two- and one-dimensional honeycomb structures of silicon and germanium. Phys. Rev. Lett. 102, 236804 (2009).
Tang, S. & Dresselhaus, M. S. Constructing anisotropic single-Dirac-cones in Bi1–xSbx thin films. Nano Lett. 12, 2021–2026 (2012).
Acknowledgements
The authors acknowledge financial support from the Ministry of Science and Technology of China (MoST, grants 2012CB933401 and 2014CB643502), the National Natural Science Foundation of China (NSFC, grants 91433101, 21374050 and 51273093) and the Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT, IRT1257). The authors thank Z. Li (Tsinghua University) for help with X-ray photoelectron spectroscope and X. Kong (Nankai University) and H. Li (Dalian Institute of Chemical Physics, Chinese Academy of Sciences) for mass spectrum measurements.
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Y.C. conceived and directed the study. T.Z. and H.C. carried out most of the experiments and data analysis. Y.W. carried out some initial experiments. T.Z. and Y.C., together with H.C., prepared most of the manuscipt. H.C. synthesized most of the samples and prepared the movies. Y.W., P.X., N.Y. and Y.L. participated in some experiments, data analysis and discussions. K.Z., X.Y. and Z.L. participated in current measurements. All authors participated in project discussions and production of the final manuscript.
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A Chinese patent based on this work has been filed (application no. CN2014105392945).
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Zhang, T., Chang, H., Wu, Y. et al. Macroscopic and direct light propulsion of bulk graphene material. Nature Photon 9, 471–476 (2015). https://doi.org/10.1038/nphoton.2015.105
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DOI: https://doi.org/10.1038/nphoton.2015.105
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