Merging the advantages of homogeneous and heterogeneous catalysts is a useful strategy for creating improved catalytic systems. Now, a concept has been developed that uses single Pd atoms — supported within liquid alloy droplets — that emerge from the droplet subsurface and interior to react with molecules approaching from the gas phase.
References
Peterson, E. J. et al. Nat. Commun. 4885 (2014).
Sterrer, M. et al. Phys. Rev. Lett. 98, 096107 (2007).
Bruix, A. et al. Angew. Chem. Int. Ed. 53, 10525 (2014).
Bliem, R. et al. Angew. Chem. Int. Ed. 54, 13999–14002 (2015).
Soma-Noto, Y. & Sachtler, W. M. H. J. Catal. 32, 315–324 (1974).
Kugler, E. L. & Boudart, M. J. Catal. 59, 201–210 (1979).
Chen, M. S., Kumar, D., Yi, C.W. & Goodman, D. W. Science 310, 291–293 (2005).
Kyriakou, G. et al. Science 335, 1209–1212 (2012).
Taccardi. et al. Nat. Chem. 9, 862–867 (2017).
Armbrüster, M., Schlögl, R. & Grin, Y. Sci. Technol. Adv. Mater. 15, 034803 (2014).
Föttinger, K. & Rupprechter, G. Acc. Chem. Res. 47, 3071–3079 (2014).
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Rupprechter, G. Popping up to the surface. Nature Chem 9, 833–834 (2017). https://doi.org/10.1038/nchem.2849
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DOI: https://doi.org/10.1038/nchem.2849
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