Defect-free Sierpiński triangles can be self-assembled on a silver surface through a combination of molecular design and thermal annealing. Three-fold halogen-bonding arrays and precise surface epitaxy preclude structural errors, thus enabling the high-level complexity of these supramolecular fractal patterns.
References
Libbrecht, K. G. Rep. Prog. Phys. 68, 855–895 (2005).
Rothemund, P. W. K., Papadakis, N. & Winfree, E. PLoS Biol 2, e424 (2004).
Lathrop, J. I., Lutz, J. H. & Summers, S. M. Theor. Comput. Sci. 410, 384–405 (2009).
Shang, J. et al. Nature Chem. 7, 389–393 (2015).
Nieckarz, D. & Szabelski, P. Chem. Commun. 50, 6843–6845 (2014).
Hirsch, B. E., McDonald, K. P., Flood, A. H. & Tait, S. L. J. Chem. Phys. 142, 101914 (2015).
Conversano, E. & Tedeschini-Lalli, L. Aplimat J. Appl. Math. 4, 113–122 (2011).
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Tait, S. Self-assembling Sierpiński triangles. Nature Chem 7, 370–371 (2015). https://doi.org/10.1038/nchem.2238
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DOI: https://doi.org/10.1038/nchem.2238
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