Tying molecules together in a link results in tremendous stabilization of the radical species they can form. Six clearly distinguishable charged states — which can be interconverted reversibly — have now been observed in a densely cationic system.
References
Fahrenbach, A. C. et al. J. Am. Chem. Soc. 134, 16275–16288 (2012).
Janoschka, T., Hager, M. D. & Schubert, U. S. Adv. Mater. 24, 6397–6409 (2012).
Noviandri, I., Bolskar, R. D., Lay, P. A. & Reed, C. A. J. Phys. Chem. B 101, 6350–6358 (1997).
Barnes, J. C. et al. Science 339, 429–433 (2013).
Kosower, E. M. & Cotter, J. L. J. Am. Chem. Soc. 86, 5524–5527 (1964).
Hünig, S. Pure Appl. Chem. 15, 109–122 (1967).
Livoreil, A. et al. J. Am. Chem. Soc. 119, 12114–12124 (1997).
Cram, D. J., Tanner, M. E. & Thomas, R. Angew. Chem. Int. Ed. Engl. 30, 1024–1027 (1991).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Amabilino, D. Highly charged. Nature Chem 5, 365–366 (2013). https://doi.org/10.1038/nchem.1611
Published:
Issue Date:
DOI: https://doi.org/10.1038/nchem.1611
- Springer Nature Limited