A detailed magnetic, structural and luminescence characterization unveils that what may have looked like mere details have a significant influence on the magnetic properties of a dysprosium complex.
References
Bottrill, M., Kwok, L. & Long, N. J. Chem. Soc. Rev. 35, 557–571 (2006).
Pimentel, G. C. & Sprately, R. D. Understanding Chemistry 862 (Holden-Day, 1971).
Cucinotta, G. et al. Angew. Chem. Int. Ed. 51, 1606–1610 (2012).
Benetollo, F., Bombieri, G., Aime, S. & Botta, M. Acta Crystallogr. C 55, 353–356 (1999).
Christou, G., Gatteschi, D., Hendrickson, D. N. & Sessoli, R. Mater. Res. Soc. Bull. 25, 66–71 (2000).
Car, P-E. et al. Chem. Commun. 47, 3751–3753 (2011).
Runge, V. M. Contrast-Enhanced Clinical Magnetic Resonance Imaging (Univ. Press Kentucky, 1997).
Viswanathan, S., Kovacs, Z., Green, K. N., Ratnakar, S. J. & Sherry, A. D. Chem. Rev. 110, 2960–3018 (2010).
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Murugesu, M. The orientation is in the details. Nature Chem 4, 347–348 (2012). https://doi.org/10.1038/nchem.1341
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DOI: https://doi.org/10.1038/nchem.1341
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