Skip to main content
Log in

Catalysis

Gold unleashes the power of three

  • News & Views
  • Published:

From Nature

View current issue Submit your manuscript

Gold in the +3 oxidation state is scarcely used in catalysis, because the oxidants employed to generate it can damage reactants. An oxidant-free route to gold(III) catalysts reveals their potential. See Article p.449

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1: Preparation and application of a gold(III) catalyst.

References

  1. Wu, C.-Y., Horibe, T., Jacobsen, C. B. & Toste, F. D. Nature 517, 449–454 (2015).

    Article  ADS  CAS  Google Scholar 

  2. Hickman, A. J. & Sanford, M. S. Nature 484, 177–185 (2012).

    Article  ADS  CAS  Google Scholar 

  3. Corma, A., Leyva-Pérez, A. & Sabater, M. J. Chem. Rev. 111, 1657–1712 (2011).

    Article  CAS  Google Scholar 

  4. Gaillard, S., Salwin, A. M. Z., Bonura, A. T., Stevens, E. D. & Nolan, S. P. Organometallics 29, 394–402 (2010).

    Article  CAS  Google Scholar 

  5. Wolf, W. J., Winston, M. S. & Toste, F. D. Nature Chem. 6, 159–164 (2013).

    Article  ADS  Google Scholar 

  6. Perthuisot, C. et al. J. Mol. Catal. A 189, 157–168 (2002).

    Article  CAS  Google Scholar 

  7. Yamamoto, H. (ed.) Lewis Acids in Organic Synthesis (Wiley, 2000).

    Book  Google Scholar 

  8. Akagawa, K., Sen, J. & Kudo, K. Angew. Chem. Int. Edn 52, 11585–11588 (2013).

    Article  CAS  Google Scholar 

  9. Pennell, M. N., Unthank, M. G., Turner, P. & Sheppard, T. D. J. Org. Chem. 76, 1479–1482 (2011).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Nicolai Cramer.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kourra, C., Cramer, N. Gold unleashes the power of three. Nature 517, 440–441 (2015). https://doi.org/10.1038/517440a

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/517440a

  • Springer Nature Limited

Navigation