Skip to main content
Log in

Theoretical chemistry

The six-bond bound

  • News & Views
  • Published:

From Nature

View current issue Submit your manuscript

What is the maximum number of covalent chemical bonds that two atoms can share? Six, according to the latest theoretical study — at least where just two atoms of the same element are concerned.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1: Six bonds that bind.

References

  1. Mierzecki, R. The Historical Development of Chemical Concepts (Kluwer, Dordrecht, 1990).

    Google Scholar 

  2. Cotton, F. A. & Harris, C. B. Inorg. Chem. 4, 330–333 (1965).

    Article  CAS  Google Scholar 

  3. Nguyen, T. et al. Science 310, 844–847 (2005).

    Article  ADS  CAS  Google Scholar 

  4. Brynda, M., Gagliardi, L., Widmark, P.-O., Power, P. P. & Roos, B. O. Angew. Chem. Int. Edn 45, 3804–3807 (2006).

    Article  CAS  Google Scholar 

  5. Frenking, G. Science 310, 796–797 (2005).

    Article  CAS  Google Scholar 

  6. Roos, B. O., Borin, A. C. & Gagliardi, L. Angew. Chem. Int. Edn 46, 1469–1472 (2007).

    Article  CAS  Google Scholar 

  7. Lewis, G. N. J. Am. Chem. Soc. 38, 762–785 (1916).

    Article  CAS  Google Scholar 

  8. Frenking, G. & Shaik, S. (eds) 90 Years of Chemical Bonding; J. Comput. Chem. 28 (2007).

  9. Heitler, W. & London, F. Z. Phys. 44, 455–472 (1927).

    Article  ADS  CAS  Google Scholar 

  10. Frenking, G. Theor. Chem. Acc. 103, 177–179 (2000).

    CAS  Google Scholar 

  11. Frenking, G. & Krapp, A. J. Comput. Chem. 28, 15–24 (2007).

    Article  CAS  Google Scholar 

  12. Krapp, A., Bickelhaupt, F. M. & Frenking, G. Chem. Eur. J. 12, 9196–9216 (2006).

    Article  CAS  Google Scholar 

  13. Kutzelnigg, W. Angew. Chem. Int. Edn Engl. 23, 272–295 (1984).

    Article  Google Scholar 

  14. Pyykkö, P. Chem. Rev. 88, 563–594 (1988).

    Article  Google Scholar 

  15. Cotton, F. A., Murillo, C. A. & Walton, R. A. Multiple Bonds Between Metal Atoms (Springer, Heidelberg, 2005).

    Book  Google Scholar 

  16. Langmuir, I. Science 54, 59–67 (1921).

    Article  ADS  CAS  Google Scholar 

  17. Dognon, J.-P., Clavaguéra, C. & Pyykkö, P. Angew. Chem. Int. Edn 46, 1427–1430 (2007).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Frenking, G., Tonner, R. The six-bond bound. Nature 446, 276–277 (2007). https://doi.org/10.1038/446276a

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/446276a

  • Springer Nature Limited

This article is cited by

Navigation