Abstract
THE unique role that gold plays in society is to a large extent related to the fact that it is the most noble of all metals: it is the least reactive metal towards atoms or molecules at the interface with a gas or a liquid. The inertness of gold does not reflect a general inability to form chemical bonds, however—gold forms very stable alloys with many other metals. To understand the nobleness of gold, we have studied a simple surface reaction, the dissociation of H2 on the surface of gold and of three other metals (copper, nickel and platinum) that lie close to it in the periodic table. We present self-consistent density-functional calculations of the activation barriers and chemisorption energies which clearly illustrate that nobleness is related to two factors: the degree of filling of the antibonding states on adsorption, and the degree of orbital overlap with the adsorbate. These two factors, which determine both the strength of the adsorbate-metal interaction and the energy barrier for dissociation, operate together to the maxima] detriment of adsorbate binding and subsequent reactivity on gold.
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References
Hayden, B. E. & Lamont, C. L. A. Phys. Rev. Lett. 63, 1823–1825 (1989).
Hodgson, A., Moryl, J., Traversaro, P. & Zhao, H. Nature 356, 501–504 (1992).
Michelsen, H. A., Rettner, C. T. & Auerbach, D. J. Phys. Rev. Lett. 69, 2678–2681 (1992).
Michelsen, H. A., Rettner, C. T., Auerbach, D. J. & Zare, R. N. J. Chem. Phys. 98, 8294–8307 (1993).
Berger, H. F., Leisch, M., Winkler, A. & Rendulic, K. D. Chem. Phys. Lett. 175, 425–428 (1990).
Robota, H. J., Vielhaber, W., Lin, M. C., Segner, J. & Ertl, G. Surf. Sci. 155, 101–120 (1985).
Brown, J. K., Luntz, A. & Schultz, P. A. J. chem. Phys. 95, 3767–3774 (1991).
Jaffey, D. M. & Madix, R. J. Surf. Sci. 311, 159–171 (1994).
Hammer, B., Scheffler, M., Jacobsen, K. W. & Nørskov, J. K. Phys. Rev. Lett. 73, 1400–1403 (1994).
White, J. A., Bird, D. M., Payne, M. C. & Stich, I. Phys. Rev. Lett. 73, 1404–1407 (1994).
Gross, A., Hammer, B., Scheffler, M. & Brenig, W. Phys. Rev. Lett. 73, 3121–3124 (1994).
Feibelman, P. J. & Harris, J. Nature 372, 135–136 (1994).
Hammer, B. & Scheffler, M. Phys. Rev. Lett. 74, 3487–3490 (1995).
Lundqvist, B. I., Gunnarsson, O., Hjelmberg, H. & Nørskov, J. K. Surf. Sci. 89, 196–225 (1979).
Holloway, S., Lundqvist, B. I. & Nørskov, J. K. in Proc. int. Congr. on Catalysis 85–95 (Chemie, Berlin, 1984).
Nørskov, J. K. Rep. Prog. Phys. 53, 1253–1295 (1990).
Andersen, O. K., Jepsen, O. & Glötzel, D. Highlights of Condensed Matter Theory Vol. LXXXIX 59 (Corso Soc. Italiana di Fisica, Bologna, 1985).
Nørskov, J. K. J. chem. Phys. 90, 7461–7471 (1989).
Hammer, B. & Nørskov, J. K. Surf. Sci. (submitted).
Payne, M. C., Teter, M. P., Allan, D. C., Arias, T. A. & Joannopoulos, J. D. Rev. mod. Phys. 64, 1045–1097 (1992).
Perdew, J. P. et al. Phys. Rev. B46, 6671–6687 (1992).
Kittel, C. Introduction to Solid State Physics (Wiley, New York, 1968).
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Hammer, B., Norskov, J. Why gold is the noblest of all the metals. Nature 376, 238–240 (1995). https://doi.org/10.1038/376238a0
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DOI: https://doi.org/10.1038/376238a0
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