Skip to main content
Log in

Chemistry

On the threshold of stability

  • News & Views
  • Published:

From Nature

View current issue Submit your manuscript

Carbenes are short-lived compounds containing a highly reactive carbon atom, which makes them difficult to study. A stabilized derivative may lead to new magnetic materials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1: Stabilization of carbenes.
Figure 2: Carbenes that can almost be bottled.

References

  1. Tomioka, H., Iwamoto, E., Itakura, H. & Hirai, K. Nature 412, 626–628 (2001).

    Article  CAS  Google Scholar 

  2. Doering, W. v. E., Buttery, R. G., Laughlin, R. G. & Chaudhuri, N. J. Am. Chem. Soc. 78, 3224 (1956).

    Article  CAS  Google Scholar 

  3. Igau, A., Grützmacher, H., Baceiredo, A. & Bertrand, G. J. Am. Chem. Soc. 110, 6463–6466 (1988).

    Article  CAS  Google Scholar 

  4. Arduengo, A. J. III, Harlow, R. L. & Kline, M. J. Am. Chem. Soc. 113, 361–363 (1991).

    Article  CAS  Google Scholar 

  5. Dixon, D. A., Dobbs, K. D., Arduengo, A. J. III & Bertrand, G. J. Am. Chem. Soc. 113, 8782–8785 (1991).

    Article  CAS  Google Scholar 

  6. Doetschman, D. C. & Hutchison, C. A. Jr J. Chem. Phys. 56, 3964–3982 (1972).

    Article  CAS  Google Scholar 

  7. Zimmerman, H. E. & Paskovich, D. H. J. Am. Chem. Soc. 86, 2149–2160 (1964).

    Article  CAS  Google Scholar 

  8. Wasserman, E. et al. J. Am. Chem. Soc. 93, 6335–6337 (1971).

    Article  CAS  Google Scholar 

  9. Hirai, K. & Tomioka, H. J. Am. Chem. Soc. 121, 10213–10214 (1999).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Heinz D. Roth.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Roth, H. On the threshold of stability. Nature 412, 598–601 (2001). https://doi.org/10.1038/35088170

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/35088170

  • Springer Nature Limited

Navigation