Abstract
USING an acoustical interferometer (frequency of the quartz crystal, 539·6 kc./s.), we have measured the velocity of sound in various liquids (carbon tetrachloride, benzene, ethyl ether and carbon disulphide) between 80° C. and the melting point of these liquids (see Fig. 1). In order to check the degree of association of the liquids at low temperatures, we computed from our measurements the relative association: R = (vm1/3/dm) /(v1/3/d), using the empirical equation of Rao1, which has also been applied by Weissler2.
Similar content being viewed by others
References
Rao, R. M. R., Ind. J. Phys., 14, 109 (1940).
Weissler, A. . J. Chem. Phys., 15, 210 (1947).
Isnard, Cont. est cienc. fis. mat., 3, 107 (1922).
Meyer, E. H. L., Ann. d. Phys., 75, 801 (1924).
Richards, Speyers and Carver, J. Amer. Chem. Soc., 46, 1203 (1924).
Findley, J. C., Pitt, A., Grayson Smith, H., and Wilhelm, J. O., Phys. Rev., 54, 506 (1938); 56, 122 (1939).
Pellam, J. R., and Squire, C. F., Phys. Rev., 72, 1241 (1947).
Keesom, W. H., and Keesom, Miss A. P., Comm. Leiden, No. 224 d; Proc. Roy. Acad. Amst., 38, 482 (1933).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
VAN ITTERBEEK, A., DE BOCK, A. Sound Velocity and Temperature Change of Molecular Association. Nature 162, 611–612 (1948). https://doi.org/10.1038/162611a0
Issue Date:
DOI: https://doi.org/10.1038/162611a0
- Springer Nature Limited
This article is cited by
-
Temperature dependence of ultrasonic velocity in liquid mixtures
Proceedings of the Indian Academy of Sciences - Section A (1952)