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Rhodium(I) Tristyrylphosphine Cyclooctadiene Complexes

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Abstract

Rhodium complexes with unsaturated phosphines as ligands were studied by NMR spectroscopy. Tris[(E,Z,Z)-styryl)phosphine is a stronger complex-forming agent compared with tris[(Z,Z,Z)-styryl)phosphine in view of the easier accessibility of its lone electron pair. The composition of the complexes and their NMR parameters suggest a square-planar structure with cis phosphine ligands.

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REFERENCES

  1. Herrmann, W.A. and Cornils, V., Angew. Chem., Int. Ed. Engl., 1997, vol. 109, no. 10, p. 1074.

    Google Scholar 

  2. Gusarova, N.K., Malysheva, S.F., Arbuzova, S.N., and Trofimov, B.A., Izv. Ross. Akad. Nauk, Ser. Khim., 1998, no. 9, p. 1695.

  3. Trofimov, V.A., Gusarova, N.K., Arbuzova, S.N., Malysheva, S.F., den Besten, R., and Brandsma, L., Synthesis, 1995, no. 4, p. 387.

  4. Gusarova, N.K., Sukhov, B.G., Malysheva, S.F., Smetannikov, Yu.V., Tarasova, N.P., and Trofimov, B.A., Zh. Obshch. Khim., 2001, vol. 71, no. 5, p. 768.

    Google Scholar 

  5. Gusarova, N.K., Arbuzova, S.N., Shaikhudinova, S.I., Malysheva, S.F., Rakhmatulina, T.N., Zinchenko, S.V., Dmitriev, V.I., and Trofimov, B.A., Zh. Obshch. Khim., 1993, vol. 63, no. 8, p. 1753.

    Google Scholar 

  6. Brown, J.M., Chaloner, P.A., Kent, A.G., Murrer, V.A., Nicholson, P.N., Parker, D., and Sidebottom, P.J., J. Organomet. Chem., 1981, vol. 216, no. 2, p. 263.

    Google Scholar 

  7. Nindakova, L.O., Shainyan, B.A., Albanov, A.I., and Ustinov, M.V., Zh. Org. Khim., 2000, vol. 36, no. 11, p. 1660.

    Google Scholar 

  8. Nindakova, L.O., Shainyan, B.A., and Albanov, A.I., Izv. Ross. Akad. Nauk, Ser. Khim., 2001, no. 10, p. 1772.

  9. Samitov, Yu.Yu., Stereospetsifichnost' konstant yadernogo spinspinovogo vzaimodeistviya i konformatsionnyi analiz (Stereospecificity of Nuclear Spin-Spin Coupling Constants and Conformational Analysis), Kazan: Kazan. Gos. Univ., 1990.

    Google Scholar 

  10. Dunkan, M. and Gallagher, M.J., Org. Magn. Reson., 1981, vol. 15, no. 1, p. 37.

    Google Scholar 

  11. Chatt, J. and Venanzi, L.M., J. Chem. Soc., 1957, no. 12, p. 4735.

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  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

    L. O. Nindakova, B. A. Shainyan, A. I. Albanov, S. F. Malysheva, B. G. Sukhov & B. A. Trofimov

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  1. L. O. Nindakova
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  2. B. A. Shainyan
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  3. A. I. Albanov
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  4. S. F. Malysheva
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  5. B. G. Sukhov
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  6. B. A. Trofimov
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Nindakova, L.O., Shainyan, B.A., Albanov, A.I. et al. Rhodium(I) Tristyrylphosphine Cyclooctadiene Complexes. Russian Journal of General Chemistry 74, 838–841 (2004). https://doi.org/10.1023/B:RUGC.0000042601.87737.54

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  • DOI: https://doi.org/10.1023/B:RUGC.0000042601.87737.54

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