Abstract
We study the analyticity properties of the free energy f γ (m) of the Kac model at points of first order phase transition, in the van der Waals limit γ↘0. We show that there exists an inverse temperature β 0 and γ 0>0 such that for all β≥β 0 and for all γ∈(0,γ 0), f γ (m) has no analytic continuation along the path m↘m * (m * denotes spontaneous magnetization). The proof consists in studying high order derivatives of the pressure p γ (h), which is related to the free energy f γ (m) by a Legendre transform.
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References
J. Bricmont, K. Kuroda, and J. L. Lebowitz, First order phase transitions in lattice and continuous systems: Extension of PirogovüSinai theory, Commun. Math. Phys. 101:501–538 (1985).
J. Bricmont and J. Slawny, Phase transitions in systems with a finite number of dominant ground states, J. Statist. Phys. 54:89–161 (1989).
A. Bovier and M. Zahradník, The low-temperature phases of KacüIsing models, J. Statist. Phys. 87:311–332 (1997).
A. Bovier and M. Zahradník, PirogovüSinai theory for long range spin systems, Markov Process. Related Fields 8:443–478 (2002).
M. Cassandro and E. Presutti, Phase transitions in ising systems with long but finite range interactions, Markov Process. Related Fields 2:241–262 (1996).
E. I. Dinaburg and Ya. G. Sinai, Contour models with interactions and applications, Selecta Math. Sovietica 7:291–315 (1988).
M. E. Fisher, The theory of condensation and the critical point, Physics 3:255–283 (1967).
S. Friedli and C.-E. Pfister, On the singularity of the free energy at first order phase transition, to appear in Commun. Math. Phys. (2003).
R. B. Griffiths, General correlation inequalities in ising ferromagnets I & II, J. Math. Phys. 8:478–483 (1967). D. G. Kelly and S. Sherman, General griffiths inequalities on correlations in ising ferromagnets, J. Math. Phys. 9:466–484 (1968).
S. N. Isakov, Nonanalytic features of the first order phase transition in the ising model, Commun. Math. Phys. 95:427–443 (1984).
S. N. Isakov, Phase diagrams and singularity at the point of a phase transition of the first kind in lattice gas models, Teoret. Mat. Fiz. 71:426–440 (1987).
K. Kuratowski, Topology, Vols. 1 and 2 (Academic Press, 1968).
M. Kac, G. E. Uhlenbeck, and P. C. Hemmer, On the van der Waals theory of the vapor-liquid equilibrium, J. Math. Phys. 4:216–228 (1963).
J. S. Langer, Theory of the condensation point, Ann. Physics 41:108–157 (1967).
J. L. Lebowitz, A. E. Mazel, and E. Presutti, Liquid-vapor phase transitions for systems with finite range interactions, J. Statist. Phys. 94:955–1025 (1999).
J. L. Lebowitz and O. Penrose, Rigorous treatment of the van ver WaalsüMaxwell theory of the liquid-vapor transition, J. Math. Phys. 7:98–113 (1966).
C. N. Yang and T. D. Lee, Statistical theory of state and phase transition I & II, Phys. Rev. 87:404–419 (1952).
C.-E. Pfister, Large deviations and phase separation in the two dimensional ising model, Helv. Phys. Acta 64:953–1054 (1991).
E. Presutti, From Statistical Mechanics to Continuum Mechanics, Lecture Notes (Max Planck Institute, Leipzig, 1999).
S. A. Pirogov and Ya. G. Sinai, Phase diagrams of classical lattice systems, Teoret. Mat. Fiz. 26:61–76 (1976).
Remmert, Theory of Complex Functions (Springer-Verlag, 1991).
J. D. van der Waals, De Continuiteit van den Gas en Vloeistoftoestand, Academic Thesis (Leiden, 1873).
M. Zahradník, An alternate version of PirogovüSinai theory, Commun. Math. Phys. 93:559–581 (1984).
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Friedli, S., Pfister, CE. Non-Analyticity and the van der Waals Limit. Journal of Statistical Physics 114, 665–734 (2004). https://doi.org/10.1023/B:JOSS.0000012506.98828.dd
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DOI: https://doi.org/10.1023/B:JOSS.0000012506.98828.dd