Abstract
The rotational Smoluchowski equation for the orientational distribution function of two dipoles with classical Heisenberg interaction is solved exactly. The equilibrium self- and pair time-correlation functions of the two dipole moments are evaluated. They are shown to be approximated well over a wide range of interaction strength by a superposition of two exponentials.
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Felderhof, B.U., Löhn, C. Rotational Brownian Motion of a Pair of Dipoles Coupled via a Classical Heisenberg Interaction. Journal of Statistical Physics 110, 1099–1115 (2003). https://doi.org/10.1023/A:1022196810741
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DOI: https://doi.org/10.1023/A:1022196810741