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Low Temperature Specific Heat Capacity of 3d Transition Metal Chlorine Boracites (T3B7O13Cl; T=Cr, Mn, Fe, Co, Ni, Cu, Zn or Mg)

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Abstract

The heat capacities of eight chlorine boracites T3B7O13Cl (T=Cr, Mn, Fe, Co, Ni, Cu, Zn or Mg) have been measured in the temperature range 2 to 100 K. Magnetic phase transitions occur below 20 K in the compounds studied except in the two non-magnetic substances Zn3B7O13Cl and Mg3B7O13Cl. The magnetic specific heat capacities give information on magnetic ground state of the transition metals and the entropy related to the phase transitions.

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Authors and Affiliations

  1. Max-Planck-Institut für Festkörperforschung, Heisenbergstr. 1, D-70569, Stuttgart, Germany

    W. Schnelle & E. Gmelin

  2. Dept. de Chimie Minérale, Analytique et Appliquée, Université de Genève, 30 Quai Ernest-Ansermet, CH-1211, Genève 4, Switzerland

    O. Crottaz & H. Schmid

Authors
  1. W. Schnelle
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  2. E. Gmelin
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  3. O. Crottaz
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  4. H. Schmid
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Schnelle, W., Gmelin, E., Crottaz, O. et al. Low Temperature Specific Heat Capacity of 3d Transition Metal Chlorine Boracites (T3B7O13Cl; T=Cr, Mn, Fe, Co, Ni, Cu, Zn or Mg). Journal of Thermal Analysis and Calorimetry 56, 365–370 (1999). https://doi.org/10.1023/A:1010158919499

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  • DOI: https://doi.org/10.1023/A:1010158919499

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