Abstract
We investigate the stochastic counterpart of the Smoluchowski coagulation equation, namely the Marcus–Lushnikov coagulation model. It is believed that for a broad class of kernels, all particles are swept into one huge cluster in an arbitrarily small time, which is known as a complete and instantaneous gelation phenomenon. Indeed, Spouge (also Domilovskii et al. for a special case) conjectured that K(i, j)=(ij)α, α>1, are such kernels. In this paper, we extend the above conjecture and prove rigorously that if there is a function ψ(i, j), increasing in both i and j such that ∑∞ j=1 1/(jψ(i, j))<∞ for all i, and K(i, j)≥ijψ(i, j) for all i, j, then complete and instantaneous gelation occurs. Evidently, this implies that any kernels K(i, j)≥ij(log(i+1)log(j+1))α, α>1, exhibit complete instantaneous gelation. Also, we conjuncture the existence of a critical (or metastable) sol state: if lim i+j→∞ ij/K(i, j)=0 and ∑∞ i, j=1 1/K(i, j)=∞, then gelation time T g satisfies 0<T g<∞. Moreover, the gelation is complete after T g.
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Jeon, I. Spouge's Conjecture on Complete and Instantaneous Gelation. Journal of Statistical Physics 96, 1049–1070 (1999). https://doi.org/10.1023/A:1004640317274
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DOI: https://doi.org/10.1023/A:1004640317274