Abstract
Any truncated-path-integral partition function of a nonrelativistic quantum system in thermodynamic equilibrium—one obtained by means of the Feynman path-integral-procedure using a finite number of such integrals—is known to have a value not less than that of the exact one corresponding to it. A rigorous asymptotic lower bound obtained for the relative disparity in their values—the difference in their values divided by that of the exact partition function— confirms asymptotic positive-definiteness of the original upper bound. Values determined directly for a linear harmonic oscillator agree asymptotically with values of they bound.
Similar content being viewed by others
REFERENCES
R. P. Feynman, Rev. Mod. Phys. 20:367–87 (1948).
R. P. Feynman and A. R. Hibbs, Quantum Mechanics and Path Integrals (McGraw-Hill, New York, 1965), Chapter 10.
R. P. Feynman and A. R. Hibbs, ref. 2, p. 31.
B. J. Berne and D. Thirumalai, Ann. Rev. Phys. Chem. 37:401–24 (1985).
D. Chandler and K. Leung, Ann. Rev. Phys. Chem. 45:557–91 (1994).
B. J. Berne and D. Thirumalai, ref. 4, p. 402.
S. Golden, Phys. Rev. 137:B1127–1128 (1965).
C. J. Thompson, J. Math. Phys. 6:1812–1813 (1965).
K. Symanzik, J. Math. Phys. 6, 1155–1156 (1965).
G. Roepstorff, Path Integral Approach to Quantum Physics, An Introduction (Springer-Verlag, Berlin, 1994) pp. 66–67, 160, 176.
K. S. Schweizer, R. M. Stratt, D. Chandler, and P. G. Wolynes, J. Chem. Phys. 75:1347–1364 (1981), especially Table 1.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Golden, S. Asymptotic Lower Bound for the Relative Disparities of Truncated-Path-Integral Partition Functions. Journal of Statistical Physics 95, 495–502 (1999). https://doi.org/10.1023/A:1004550100048
Issue Date:
DOI: https://doi.org/10.1023/A:1004550100048