Abstract
More than two decades ago, in a seminal paper John Cahn proposed scaling arguments for the possibility of a wetting transition in two coexisting fluid phases near the critical point. Since then, Cahn's model has been tested in many fluid systems and further refined by including the real interactions between the fluid and the solid wall. A fascinating consequence of the existence of a wetting transition is the possibility for a transition from weak to strong adsorption in the homogeneous phase. The situation is further enriched in nonstandard geometries having special geometrical constraints. The subject of this review concerns one such situation, where charge-stabilized colloidal particles are suspended in the homogeneous region of a binary liquid mixture. In this case, the preferential adsorption of one of the liquid components on to the colloid surface completely modifies the stability of the particles leading to an aggregation process. Although the exact mechanism underlying the adsorption phenomenon is still debated, it is closely related to the wetting transition. Recent experimental developments concerning the static and dynamic aspects of this phenomenon are reviewed. In addition, the main findings of a theoretical model based on the adsorption-modified electrostatic interactions between the colloidal particles are discussed.
Similar content being viewed by others
REFERENCES
J. W. Cahn, J. Chem. Phys. 66:3667 (1977).
C. Ebner, and W. F. Saam, Phys. Rev. Lett. 38:1486 (1977).
S. Dietrich, in Phase Transitions and Critical Phenomena, Vol. 12, C. Domb and J. L. Lebowitz, eds. (Academic Press, 1988), p. 1.
Liquids at Interfaces, Les Houches Session XLVIII, J. Charvolin, J.-F. Joanny, and J. Zinn-Justin, eds. (North Holland, 1990).
M. P. Gelfand and R. Lipowsky, Phys. Rev. B 36:8725 (1985).
P. J. Upton, J. O. Indekeu, and J. M. Yeomans, Phys. Rev. B 40:666 (1989).
H. T. Dobbs and J. M. Yeomans, J. Phys.: Condens. Matter 4:10133 (1992).
H. T. Dobbs, G. A. Darbellay, and J. M. Yeomans, Europhys. Lett. 18:439 (1992).
D. Beysens, J.-M. Petit, T. Narayanan, A. Kumar, and M. Broide, Ber. Bunsenges Phys. Chem. 98:382 (1994).
D. Beysens and D. Estève, Phys. Rev. Lett. 54:2123 (1985).
V. Gurfein, D. Beysens, and F. Perrot, Phys. Rev. A 40:2543 (1989).
J. S. van Duijneveldt and D. Beysens, J. Chem. Phys. 94:5222 (1991).
P. D. Gallagher and J. V. Maher, Phys. Rev. A 46:2012 (1992); P. D. Gallagher, M. L. Kurnaz, and J. V. Maher, Phys. Rev. A 46:7750 (1992).
T. Narayanan, A. Kumar, E. S. R. Gopal, D. Beysens, P. Guenoun, and G. Zalczer, Phys. Rev. E 48:1989 (1993).
S. R. Kline and E. W. Kaler, Langmuir 10:412, (1994).
Y. Jayalakshmi and E. W. Kaler, Phys. Rev. Lett. 78:1379 (1997).
B. Rathke, H. Grüll, and D. Woermann, J. Colloid Interface Sci. 192:334 (1997).
R. D. Koehler and E. W. Kaler, Langmuir 13:2463 (1997).
M. L. Broide, Y. Garrabos, and D. Beysens, Phys. Rev. E 47:3768 (1993).
T. Narayanan, J.-M. Petit, M. L. Broide, and D. Beysens, Phys. Rev. E 51:4580 (1995).
M. L. Kurnaz and J. V. Maher, Phys. Rev. E 55:572 (1997); ibid 51:5916 (1995).
T. J. Sluckin, Phys. Rev. A 41:960 (1990). See also E. A. Boucher, J. Chem. Soc. Faraday Trans. I 85:2963 (1989).
H. Löwen, Phys. Rev. Lett. 74:1028 (1995).
R. R. Netz, Phys. Rev. Lett. 76:3646 (1996).
T. Gil, J. H. Ipsen, and C. F. Tejero, Phys. Rev. E 57:3123 (1998).
T. Bieker and S. Dietrich, Physica A 252:85 (1998).
M. E. Fisher and P. G. de Gennes, C.R. Acad. Sci. Ser. B 287:207 (1978).
T. W. Burkhardt and E. Eisenriegler, Phys. Rev. Lett. 74:3189 (1995); E. Eisenriegler, and U. Ritschel, Phys. Rev. B 51:13 717 (1995); A. Hanke, F. Schlesener, E. Eisenriegler, and S. Dietrich, Phys. Rev. Lett. 81:1885 (1998).
J.-M. Petit, B. M. Law, and D. Beysens, J. Colloid Interface Sci. 202:441 (1998).
B. M. Law, J.-M. Petit, and D. Beysens, Phys. Rev. E 57:5782 (1998).
J. Mahanty and B. W. Ninham, Dispersion Forces (Academic, London, 1976).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Beysens, D., Narayanan, T. Wetting-Induced Aggregation of Colloids. Journal of Statistical Physics 95, 997–1008 (1999). https://doi.org/10.1023/A:1004506601807
Issue Date:
DOI: https://doi.org/10.1023/A:1004506601807