Abstract
The first representative of the pyrimidine-substituted [60]fullereno[1,2-b]aziridines was synthesized by the reaction of fullerene C60 with 2-azido-4,6-diphenylpyrimidine. 2-(Azahomo[60]fullereno)-4,6-diphenylpyrimidine was found to be formed as a by-product. The electrochemical properties of the adducts were studied.
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I. P. Romanova, V. V. Kalinin, A. A. Nafikova, D. G. Yakhvarov, V. V. Zverev, V. I. Kovalenko, G. L. Rusinov, P. V. Plekhanov, V. N. Charushin, and O. G. Sinyashin, Izv. Akad. Nauk, Ser. Khim., 2003, 163 [Russ. Chem. Bull., Int. Ed., 2003, 52, 173].
U. Reuther and A. Hirsch, Carbon, 2000, 38, 1539.
M. Tisler, Synthesis, 1973, 123.
V. I. Kovalenko, in sb. statei "Struktura i dinamika molekulyarnykh sistem", ch. 2 [Collection of Articles "Structure and Dynamics of Molecular Systems," Part 2], Izd-vo MarGTU, Ioshkar-Ola, 1997, 91 (in Russian).
D. L. Smith and P. J. Elving, J. Am. Chem. Soc., 1962, 84, 2741.
O. G. Sinyashin, I. P. Romanova, G. G. Yusupova, A. A. Nafikova, V. I. Kovalenko, N. M. Azancheev, V. V. Yanilkin, and Y. G. Budnikova, Mendeleev Commun., 2000, 61.
M. W. Schmidt, K. K. Baldridge, J. A. Boatz, S. T. Elbert, M. S. Gordon, J. J. Jensen, S. Koseki, N. Matsunaga, K. A. Nguyen, S. Su, T. L. Windus, M. Dupuis, and J. A. Montgomery, J. Comput. Chem., 1993, 14, 1347.
V. L. Karnatsevich, M. A. Lopatin, A. I. Kirillov, and B. S. Kaverin, Tez. dokl. VIII Mezhdunar. konf. [Proc. VIII Intern. Conf.] ICHMS´2003 "Hydrogen Materials Science and Chemistry of Carbon Nanomaterials" (Sudak-Crimea-Ukraine, 14-20 September, 2003), Kiev, 2003, 486.
V. A. Chuiguk and T. I. Glukhova, Ukr. Khim. Zh. [Ukr. Chem. J.], 1980, 835 (in Russian).
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Romanova, I.P., Yusupova, G.G., Yakhvarov, D.G. et al. Reaction of fullerene C60 with 2-azido-4,6-diphenylpyrimidine. Russian Chemical Bulletin 52, 2171–2174 (2003). https://doi.org/10.1023/B:RUCB.0000011875.65588.6f
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DOI: https://doi.org/10.1023/B:RUCB.0000011875.65588.6f