Abstract
The thermal conductivities of nitrogen and three mixtures of nitrogen and methane at six nominal temperatures between 300 and 425 K have been measured as a function of pressure up to 16 MPa. The relative uncertainty of the thermal conductivity measurements at a 95% confidence level is estimated to be less then 1%. The data obtained and the results of the low-density analysis were used to test two prediction methods for the thermal conductivity of gas mixtures under pressure and for the thermal conductivity of dilute polyatomic gas mixtures. Reasonable agreement was found with expressions for predicting thermal conductivity of nonpolar mixtures in a dilute-gas limit developed by Schreiber et al. The scheme underestimates the experimental thermal conductivity with deviations not exceeding 3%. The prediction scheme for the thermal conductivity of gas mixtures under pressure suggested by Mason et al. and improved by Vesovic and Wakeham underestimates the experimental thermal conductivities throughout, likely due to its use of the Hirchsfelder–Eucken equation at the low-density limit.
Similar content being viewed by others
Reference
H. M. Roder and D. G. Friend, Int. J. Thermophys. 6:607(1985).
J. Kestin, Y. Nagasaka, and W. A. Wakeham, Ber. Bunsenges. Phys. Chem. 86:632(1982).
J. Kestin, S. T. Ro, and Y. Nagasaka, Ber. Bunsenges. Phys. Chem. 86:945(1982).
A. I. Johns, S. Rashid, L. Rowan, J. T. R. Watson, and A. A. Clifford, Int. J. Thermophys. 9:3(1988).
J. Pátek and J. Klomfar, Fluid Phase Equilib. 198:147(2002).
J. J. de Groot, J. Kestin, and H. Sookiazian, Physica 75:454(1974).
J. J. Healy, J. J. de Groot, and J. Kestin, Physica C 82:392(1976).
J. Kestin and W. A. Wakeham, Physica A 92:102(1978).
M. J. Assael, C. A. Nieto de Castro, H. M. Roder, and W. A. Wakeham, in Measurements of the Transport Properties of Fluids—Experimental Thermodynamics, Vol. 3, W. A. Wakeham, A. Nagashima, and J. V. Sengers, eds. (Blackwell Scientific, Oxford, 1991), pp. 164-188.
R. Span, E. W. Lemmon, R. T. Jacobsen, and W. Wagner, Int. J. Thermophys. 19:1121(1998).
Compressibility Factors of Natural Gas and Other Related Hydrocarbon Gases, A.G.A. Report No. 8, Second Ed. (Arlington, Virginia, 1992).
ISO 12 213, Natural Gas—Calculation of Compression Factor: Calculation using Molar-Composition Analysis, First Ed., Geneva (1997).
M. Bureš, R. Holub, J. Leitner, and P. Vonka, The Thermochemical Quantities of Organic Compounds (Institute of Chemical Technology Editing Center, Prague, 1992).
E. A. Mason, H. E. Khalifa, J. Kestin, R. DiPippo, and J. R. Dorfman, Physica A 91:377(1978).
M. K. Tuam and K. E. Gubins, J. Chem. Phys. 55:268(1971).
J. Kestin and W. A. Wakeham, Ber. Bunsenges. Phys. Chem. 84:762(1980).
V. Vesovic and W. A. Wakeham, High Temp. High Press. 23:179(1991).
D. G. Friend, J. F. Ely, and H. Ingham, J. Phys. Chem. Ref. Data 18:583(1989).
K. Stephan, R. Krauss, and A. Leasacke, J. Phys. Chem. Ref. Data 16:993(1987).
G. C. Mautland, E. B. Smith, M. Rigby, and W. A. Wakeham, Intermolecular Forces (Claredon Press, Oxford, 1981).
J. O. Hirschfelder, J. Chem. Phys. 26:282(1957).
J. Millat and W. A. Wakeham, J. Phys. Chem. Ref. Data 18:565(1989).
F. J. Uribe, E. A. Mason, and J. Kestin, J. Phys. Chem. Ref. Data 19:1123(1990).
M. Schreiber, V. Vesovic, and W. A. Wakeham, Int. J. Thermophys. 18:925(1997).
M. J. Ross, V. Vesovic, and W. A. Wakeham, Physica A 183:519(1992).
V. Vesovic, High Temp. High Press. 32:163(2000).
M. J. Assael, J. Millat, V. Vesovic, and W. A. Wakeham, J. Phys. Chem. Ref. Data 19:1137(1990).
B. Le Neindre, Int. J. Heat Mass Transfer 15:1(1972).
J. W. Haarman, auP Conf. Proc. 11:193(1973).
A. A. Clifford, J. Kestin, and W. A. Wakeham, Physica A 97:287(1979).
A. A. Clifford, P. Gray, A. I. Johns, A. C. Scott, and J. T. R. Watson, J. Chem. Soc. Faraday Trans. 77:2679(1981).
E. N. Haran, G. C. Mautland, M. Mustafa, and W. A. Wakeham, Ber. Bunsenges. Phys. Chem. 87:657(1983).
A. I. Johns, S. Rashid, J. T. R. Watson, and A. A. Clifford, J. Chem. Soc. Faraday Trans. 82:2235(1986).
J. Millat, M. J. Ross, and W. A. Wakeham, Physica A 159:28(1989).
R. Mostert, H. R. van den Berg, and P. S. van der Gulik, Int. J. Thermophys. 11:597(1990).
R. A Perkins, H. M Roder, D. G. Friend, and C. A. Nieto de Castro, Physica A 173:322(1991).
L. Monchick, Int. J. Thermophys. 18:909(1997).
B. N. Taylor and Ch. E. Kuyatt, Guidelines for Evaluating and Expressing the Uncertaunty of NIST Measurement Result, NIST Tech. Note 1297 (1994).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Pátek, J., Klomfar, J., Čapla, L. et al. Thermal Conductivity of Nitrogen-Methane Mixtures at Temperatures Between 300 and 425 K and at Pressures Up to 16 MPa. International Journal of Thermophysics 24, 923–935 (2003). https://doi.org/10.1023/A:1025024127880
Issue Date:
DOI: https://doi.org/10.1023/A:1025024127880