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Mössbauer Study of the Structure of Fe - Zircon System

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Abstract

Iron-doped silicate (zircon), prepared by a ceramic method with the addition of LiF as mineralizer, was analyzed by X-ray powder diffraction (XRD) and 57Fe Mössbauer spectroscopy to obtain information on the solid solution formation. The results of X-ray diffraction and Mössbauer spectroscopy have shown that only a small fraction of iron, about 1.5 mol%, is incorporated in the zircon structure as paramagnetic Fe3+ species while the remaining Fe3+ cations form magnetic α-Fe2O3 particles which are trapped within the zircon matrix.

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Authors and Affiliations

  1. Instituto de Física, U.N.A.M., A.P. 1-1010, Querétaro, Querétaro, 76001.37, Mexico

    E. Carreto & V. Castaño

  2. DEPg., Facultad de Química, U.N.A.M, Universitaria Coyoacan, Circuito Escolar, Cd, 04510, D.F. México, Mexico

    C. Piña & H. Arriola

  3. Centro de Química, Ing. Química ICUAP, Edificio 76, Complejo de Ciencias, C.U. Puebla, Pue., C.P, 72570, Mexico

    A. Barahona

  4. Instituto Mexicano del Petróleo, México, D.F., Mexico

    N. Nava

Authors
  1. E. Carreto
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  2. C. Piña
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  3. H. Arriola
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  4. A. Barahona
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  5. N. Nava
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  6. V. Castaño
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Carreto, E., Piña, C., Arriola, H. et al. Mössbauer Study of the Structure of Fe - Zircon System. Journal of Radioanalytical and Nuclear Chemistry 250, 453–458 (2001). https://doi.org/10.1023/A:1017988720055

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  • DOI: https://doi.org/10.1023/A:1017988720055

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