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Application of heterogenized oxidation catalysts to reactions of terpenic and other olefins with H2O2

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Abstract

This paper discusses two heterogeneous catalysts that were designed by covalent or electrostatic immobilization of a homogeneous metal complex. The first material contains Mn–triazacyclononane complexes anchored to silica. The second material is a resin with exchanged peroxo W polyoxoanions. Topics of interest include chemoselectivity, regioselectivity and recyclability. These aspects are studied in reactions with 18 different olefin substrates, with a focus on terpene reactions.

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Authors and Affiliations

  1. Center for Surface Science and Catalysis, K.U. Leuven, Kardinaal Mercierlaan 92, 3001, Leuven, Belgium

    Bert F. Sels, Aida L. Villa, Dirk Hoegaerts, Dirk E. De Vos & Pierre A. Jacobs

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  1. Bert F. Sels
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  2. Aida L. Villa
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  3. Dirk Hoegaerts
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  4. Dirk E. De Vos
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  5. Pierre A. Jacobs
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Sels, B.F., Villa, A.L., Hoegaerts, D. et al. Application of heterogenized oxidation catalysts to reactions of terpenic and other olefins with H2O2 . Topics in Catalysis 13, 223–229 (2000). https://doi.org/10.1023/A:1009046703320

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