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Synthesis of (azidomethyl)phenylboronic acids

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Abstract

The synthesis of 2-, 3-, and 4-(azidomethyl)phenylboronic acids was carried out. The geometric and electronic structures were studied by quantum-chemical methods. The suggestion is made that there are weak intramolecular interactions between the boron atom and the nitrene nitrogen atom of the azido group.

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Authors and Affiliations

  1. N. I. Lobachevsky University of Nizhnii, Novgorod, 23 prosp. Gagarina, 603950, Nizhnii Novgorod, Russian Federation

    A. Yu. Fedorov, A. A. Shchepalov, A. V. Bol"shakov & S. V. Zelentsov

  2. G. A. Razuvaev Institute of Organometallic Chemistry of the, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation

    A. S. Shavyrin & Yu. A. Kurskii

  3. Faculty of Science of St. Jerome, Aix-Marseille University, 13397, Marseille, France

    J.-P. Finet

Authors
  1. A. Yu. Fedorov
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  2. A. A. Shchepalov
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  3. A. V. Bol"shakov
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  4. A. S. Shavyrin
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  5. Yu. A. Kurskii
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  6. J.-P. Finet
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  7. S. V. Zelentsov
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Fedorov, A.Y., Shchepalov, A.A., Bol"shakov, A.V. et al. Synthesis of (azidomethyl)phenylboronic acids. Russian Chemical Bulletin 53, 370–375 (2004). https://doi.org/10.1023/B:RUCB.0000030813.05424.1f

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  • DOI: https://doi.org/10.1023/B:RUCB.0000030813.05424.1f

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