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Caged phosphite complexes of copper(I) halides

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Abstract

The coordination chemistry of the caged phosphites 4-2,6,7-trioxa-1-phosphabicyclo [2.2.2]octane (MeCage) and 4-nitro-t2,6,7-trioxa-1t-phosphabicyclo[2.2.2]octane (NO2Caget) with copper(I) halides is reported. Reactions of CuX = CuCl, CuBr, and CuI with the phosphite ligands afford complexes of the type [CuX(MeCage)]4, [CuX(NO2Cage)]4, [CuX(MeCage)2]2, [CuX(NO2Cage)2]2, and [CuX(MeCage)3]. Recrystallization of [CuBr(NO2Cage)2]2 in MeCN produced [CuBr(NO2Cage)(NCMe)]2. Three X-ray crystal structures are reported: [CuCl(MeCage)]4 (I − 4, a = 13.4292(5) Å, b = 13.4292(5) Å, c = 9.4641(5) Å, V = 1706.79(13) Å3, Z = 2), [CuBr(MeCage)2]2 (I41/a, a = 19.5751(17) Å, b = 19.5751(17) Å, c = 16.4513(15) Å, V = 6303.9(10) Å3, Z = 8), and [CuBr(NO2Cage)(NCMe)]2 (P21/c, a = 9.0506(4) Å, b = 15.2428(7) Å, c = 8.8673(4) Å, β = 109.7640(10)○, V = 1151.24(9) Å3, Z = 2).

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References

  1. Verkade, J.G.; Reynolds, L.T. J. Org. Chem. 1960, 35, 1602.

    Google Scholar 

  2. Verkade, J.G.; Huttemann, T.J.; Fung, M.K.; King, R.W. Inorg. Chem. 1965, 4, 83.

    Google Scholar 

  3. Honig, E.D.; Quin-jin, M.; Robinson, W.T.; Williard, P.G.; Sweigart, D.A. Organometallics 1985, 4, 871.

    Google Scholar 

  4. Fang, X.; Scott, B.L.; John, K.D.; Kubas, G.J. Organometallics 2000, 19, 4141.

    Google Scholar 

  5. Tolman, C.A. Chem. Rev. 1977, 77, 313.

    Google Scholar 

  6. Hendricker, D.G. J. Heterocycl. Chem. 1967, 4, 385.

    Google Scholar 

  7. Hyde, E. M.; Swain, J.R.; Verkade, J. G.; Meakin, P. J. Chem. Soc., Dalton Trans. 1976, 1169.

  8. Verkade, J.G.; Piper, T.S. Inorg. Chem. 1962, 1, 453.

    Google Scholar 

  9. Graham, P.M.; Pike, R.D.; Sabat, M.; Bailey, R.D.; Pennington, W.T. Inorg. Chem. 2000, 39, 5121.

    PubMed  Google Scholar 

  10. SAINT +; Bruker Analytical X-ray Systems: Madison, WI, 1997.

  11. SADABS; Bruker Analytical X-ray Systems: Madison, WI, 1997.

  12. CRYSTAL CLEAR: Rigaku/Molecular Corporation, The Woodlands, Texas, 1999.

  13. Sheldrick, G.M. SHELXTL: Crystallographic Computing System, Version 5.1, Bruker Analytical X-ray Systems: Madison, WI, 1997.

  14. Pike, R.D.; Dendramis, K.D.; Cole, J.R.; Johnson, T.J.; Pennington, W.T., to be published.

  15. Pike, R.D.; Starnes, W.H., Jr.; Carpenter, G.B. Acta Crystallogr., Sect. C 1998, 55, 162; and references therein.

    Google Scholar 

  16. Gill, J.T.; Mayerle, J.J.; Welcker, P.S.; Lewis, D.F.; Ucko, D.A.; Barton, D.J.; Stowens, D.; Lippard, S.J. Inorg. Chem. 1976, 15, 1155.

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, College of William and Mary, Williamsburg, Virginia, 23187

    Jenine R. Cole, Megan E. Dellinger, T. Jason Johnson, Bryn A. Reinecke & Robert D. Pike

  2. Department of Chemistry, Clemson University, Clemson, South Carolina

    William T. Pennington & Mariusz Krawiec

  3. Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware

    Arnold L. Rheingold

Authors
  1. Jenine R. Cole
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  2. Megan E. Dellinger
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  3. T. Jason Johnson
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  4. Bryn A. Reinecke
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  5. Robert D. Pike
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  6. William T. Pennington
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  7. Mariusz Krawiec
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  8. Arnold L. Rheingold
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Correspondence to Robert D. Pike.

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Cole, J.R., Dellinger, M.E., Johnson, T.J. et al. Caged phosphite complexes of copper(I) halides. Journal of Chemical Crystallography 33, 341–347 (2003). https://doi.org/10.1023/A:1024217727932

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