Abstract
Beta barium borate (β-BBO) crystals have been grown by the top seeded solution growth technique (TSSG) using Na2O as a flux. The crystals exhibited high transparency and the absence of inclusions and found to have sodium contamination in the range 150 to 230 p.p.m. The effect of this contamination on some crystal properties of interest has been investigated. The presence of impurities causes optical absorption below 550 nm in BBO crystals of both α and β-phases. X-ray photo emission spectroscopy (XPS) measurements performed on these crystals show that sodium gives rise to a measurable shift in the binding energies of the constituent ions. Further, the results show that Na+ ions enter into the lattice substitutionally and provide charge trapping sites close to the band edge.
Similar content being viewed by others
References
H. NAKATANI, W. R. BOSENBERG, L. K. CHENG and C. L. TANG, Appl. Phys. Lett. 53 (1988) 2587.
W. MUCKENHIME, P. LOKAI, B. BURGHARDT and D. BASTING, Appl. Phys. B. 45 (1988) 259.
G. C. BHAR, U. CHATTERGEE, A. M. RUDRA, P. KUMBHAKAR, R. K. ROUTE and R. S. FEIGELSON, Opt. Lett. 22 (1997) 1606.
R. S. FEIGELSON, R. J. RAYMAKERS and R. K. ROUTE, J. Cryst. Growth 97 (1989) 352.
A. K. SANGIRI, SANGEETA, K. S. KESHWANI, D. G. DESAI, A. K. CHAUHAN, M. N. AHUJA and S. C. SABHARWAL, Solid State Phys. Symp. 40 (1997) 350.
J. K. LIANG, Y. L. ZHANG and Q. Z. HUANG, Acta. Chim. Sinica. 40 (1982) 994.
JIANG AIDONG, CHENG FEN, LIN QI, CHENG ZUSHENG and ZHENG YONG, J. Cryst. Growth 79 (1986) 963.
O. M. GUALTIERI, B. H. T. CHAI and M. H. RANDLES, ibid. 97 (1989) 613.
W. R. BOSENBERG, R. J. LANE and C. L. TANG, ibid. 108 (1991) 394.
M. ROTH and D. PERLOV, ibid. 169 (1996) 734.
D. PERLOV and M. ROTH, ibid. 137 (1994) 123.
L. K. CHENG, W. R. BOSENBERG and C. L. TANG, Prog. Cryst. Growth Charact. 20 (1990) 9.
R. S. FEIGELSON, R. J. RAYMAKERS and R. K. ROUTE, ibid. 20 (1990) 115.
L. K. CHENG, W. BOSENBERG and C. L. TANG, J. Cryst. Growth 89 (1988) 553.
S. C. SABHARWAL and SANGEETA, ibid. 187 (1998) 253.
G. ZHANG, Y. YANG and C. ZHANG, Appl. Phys. Lett. 53 (1988) 1019.
Powder diffraction file 38–722 (JCPDS-ICDD, USA, 1995).
B. D. PADALIA, P. K. METHA, S. R. REDDY, OM PRAKASH and N. VENKATARAMANI, Mod. Phys. Lett. B. 2 (1988) 1177.
C. D. WAGNER, W. M. RIGGS and L. E. DAVIS, "Handbook of X-ray Photoelectron Spectroscopy" (Perkin-Elmer Corporation, Minnesota, 1979) p. 38.
D. EIMERL, L. DAVIS, S. VELSCO, E. K. GRAHAM and A. ZALKIN, J. Appl. Phys. 62 (1987) 1968.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sabharwal, S.C., Sangeeta, Goswami, M. et al. Growth, optical transmission and X-ray photoemission studies of BaB2O4 single crystals. Journal of Materials Science: Materials in Electronics 11, 325–329 (2000). https://doi.org/10.1023/A:1008981400102
Issue Date:
DOI: https://doi.org/10.1023/A:1008981400102