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C-Alkylation by Hydrogen Autotransfer Reactions

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Abstract

The development of practical, efficient, and atom-economical methods for the formation of carbon–carbon bonds remains a topic of considerable interest in current synthetic organic chemistry. In this review, we have summarized selected topics from the recent literature with particular emphasis on C-alkylation processes involving hydrogen transfer using alcohols as alkylation reagents. This review includes selected highlights concerning recent progress towards the modification of catalytic systems for the α-alkylation of ketones, nitriles, and esters. Furthermore, we have devoted a significant portion of this review to the methylation of ketones, alcohols, and indoles using methanol. Lastly, we have also documented recent advances in β-alkylation methods involving the dimerization of alcohols (Guerbet reaction), as well as new developments in C-alkylation methods based on sp 3 C–H activation.

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  1. Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka, 564-8680, Japan

    Yasushi Obora

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  1. Yasushi Obora
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Obora, Y. C-Alkylation by Hydrogen Autotransfer Reactions. Top Curr Chem (Z) 374, 11 (2016). https://doi.org/10.1007/s41061-016-0012-8

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