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Studies on the halogen substituted β-amino acids and their Cu(II) coordination complexes in crystallography

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Abstract

Halogen substituted β-amino acids, D,L-3-amino-3-(4-fluoro)phenylpropionic acid(D,L-HL1, 1) and D,L-3-amino-3-(4-bromo)phenylpropionic acid(D,L-HL2, 2), as well as their Cu(II) coordination complexes [Cu(L1)2(CH3OH)2]·2CH3OH(3) and [Cu(L2)2(CH3OH)2]·2CH3OH(4) were investigated and their single crystal structures were discussed in details. Supramolecular helical chains were found in β-amino acids 1 and 2 while there was no helix in their coordination complexes 3 and 4. The formation of supramolecular helixes could be due to the hydrogen bonds between terminal ―NH +3 and adjacent ―COO– in β-amino acids 1 and 2. While, this kind of hydrogen bonds could not be observed in their Cu(II) coordination complexes 3 and 4, in which central-symmetrical dimers could be formed via coplanar coordinated bonds(N―Cu―O) between ―NH2 and ―COO–.

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Authors and Affiliations

  1. Key Laboratory of Cluster Science, Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry, Beijing Institute of Technology, Beijing, 100081, P. R. China

    Chunying Zheng, Qiming Qiu, Liang Hao & Hui Li

Authors
  1. Chunying Zheng
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  2. Qiming Qiu
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  3. Liang Hao
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  4. Hui Li
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Corresponding author

Correspondence to Hui Li.

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Supported by the National Natural Science Foundation of China(Nos.21071018, 21271026).

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Zheng, C., Qiu, Q., Hao, L. et al. Studies on the halogen substituted β-amino acids and their Cu(II) coordination complexes in crystallography. Chem. Res. Chin. Univ. 32, 1–7 (2016). https://doi.org/10.1007/s40242-016-5333-1

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  • DOI: https://doi.org/10.1007/s40242-016-5333-1

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