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Rapid synthesis of glycosyl bromides by ultrasound irradiation

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Chemical Research in Chinese Universities Aims and scope

Abstract

A convenient and environmentally friendly reactor for the synthesis of glycosyl bromides via ultrasound irradiation was designed. Peracetylated glycosyl bromides were synthesized from free saccharides by means of a one-pot method. Benzoylated and 6-subsituted glycosyl bromides were prepared from protected saccharides. The glycosyl bromides were obtained in isolated yields of 83% to 96%.

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Authors and Affiliations

  1. Shanxi Agricultural University, Taigu, 030801, P. R. China

    Jin-zhong Zhao, Xue-qin Zhang, Xin Wu & Ze-bing Xing

  2. Natural Products Research Center, Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, 610041, P. R. China

    Hua-wu Shao

Authors
  1. Jin-zhong Zhao
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  2. Xue-qin Zhang
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  3. Xin Wu
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  4. Ze-bing Xing
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  5. Ai-qin Yue
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  6. Hua-wu Shao
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Corresponding author

Correspondence to Jin-zhong Zhao.

Additional information

Supported by the Project of Science and Technology of Shanxi Province, China(No.20100311069), the Special Fund for the Introduced Talents of Shanxi Agricultural University, China(No.XB2009013) and the Special Fund for the Introduced Talents of Shanxi Province, China.

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Zhao, Jz., Zhang, Xq., Wu, X. et al. Rapid synthesis of glycosyl bromides by ultrasound irradiation. Chem. Res. Chin. Univ. 29, 71–75 (2013). https://doi.org/10.1007/s40242-012-2102-7

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  • DOI: https://doi.org/10.1007/s40242-012-2102-7

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