Abstract
Fan-shaped SiO2 nanowires modified SiO2@C composites with a bio-inspired hierarchical porous structure and a high accessible surface area were prepared by in situ molten salt template method. The combination of biogenic hierarchical porous structure and one-dimensional nanostructure with similar features was successfully obtained by one-pot heat treatment in the presence of rice husk SiO2 with SiO2 acting as precursor and ZnCl2 acting as molten salt and growth template. A large amount of fan-shaped SiO2 nanowires with numerous tiny branches sprouting from the central nanowires were grown in the inter-porous epidermis and on the surface of rice husk SiO2 for temperatures up to 1200 °C. The in situ ZnCl2 molten salt template base-growth mechanism is responsible for the initial formation of SiO2/ZnCl2 co-melting nanowires and the subsequent growth of fan-shaped SiO2 nanowires. The as-prepared samples have been successfully employed as organic absorbers with high efficiency in the field of wastewater treatment.
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Acknowledgements
This work was financially supported by the Key Technology R and D Program of Hubei Province (No. 2015BCA253) and the China Postdoctoral Science Foundation (No. 2015M572210) and the Open Foundation of The State Key Laboratory of Refractories and Metallurgy (No. 2014QN17).
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Chen, H., Zhao, L., He, X. et al. In situ Formed Fan-Shaped Nanowires in Biomorphic SiO2: A Multidimensional Composite of Hierarchical Porous Material and Organic Pollutant Adsorption Behavior. Acta Metall. Sin. (Engl. Lett.) 30, 104–112 (2017). https://doi.org/10.1007/s40195-016-0525-8
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DOI: https://doi.org/10.1007/s40195-016-0525-8