Abstract
Er3+/Yb3+ codoped niobium pentoxide glasses were fabricated by the aerodynamic levitation (ADL) method with rapid cooling rate. All samples with various doping concentrations showed good upconversion luminescence properties under 980 nm laser excitation. The structure, transmittance spectrum, and luminescence properties of the samples were systemically investigated by XRD, UV–Vis–NIR spectrophotometer, and upconversion spectra. All transparent samples exhibited green and red upconversion emissions centered at 532, 547, and 670 nm. Experimental results showed that the sample codoped with 1 mol% Er3+/Yb3+ has the strongest upconversion emissions, and the increase of the doped Yb3+ concentration results in the increased red emission and reduced green emission. The logI–logP plot of green emission indicated that the green emissions reach the saturation at high pump power excitation, deviating from the low-power regime. After one-photon energy transfer (ET) process, 4I11/2+4I11/2→4F7/2+4I15/2 process between the two neighboring Er3+ ions was responsible for the population of the 4S3/2/4H11/2 states. The niobium pentoxide codoped with Er3+/Yb3+ bulk glasses could be used in the dye sensitized solar cell (DSSC) to improve the efficiency.
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Rodríguez-Rodríguez H, Imanieh MH, Lahoz F, et al. Analysis of the upconversion process in Tm3+ doped glasses for enhancement of the photocurrent in silicon solar cells. Sol Energ Mat Sol C 2016, 144: 29–32.
Tikhomirov VK, Rodriguez VD, Mendez-Ramos J, et al. Optimizing Er/Yb ratio and content in Er–Yb co-doped glass-ceramics for enhancement of the up- and down-conversion luminescence. Sol Energ Mat Sol C 2012, 100: 209–215.
Maji SK, Sreejith S, Joseph J, et al. Upconversion nanoparticles as a contrast agent for photoacoustic imaging in live mice. Adv Mater 2014, 26: 5633–5638.
Sarakovskis A, Krieke G. Upconversion luminescence in erbium doped transparent oxyfluoride glass ceramics containing hexagonal NaYF4 nanocrystals. J Eur Ceram Soc 2015, 35: 3665–3671.
Chen D, Wan Z, Zhou Y, et al. Tailoring Er3+ spectrally pure upconversion in bulk nano-glass-ceramics via lanthanide doping. J Eur Ceram Soc 2016, 36: 679–688.
Dey R, Pandey A, Rai VK. The Er3+–Yb3+ codoped La2O3 phosphor in finger print detection and optical heating. Spectrochim Acta A 2014, 128: 508–513.
Singh SK, Kumar K, Rai SB. Multifunctional Er3+–Yb3+ codoped Gd2O3 nanocrystalline phosphor synthesized through optimized combustion route. Appl Phys B 2009, 94: 165–173.
Nyk M, Kumar R, Ohulchanskyy TY, et al. High contrast in vitro and in vivo photoluminescence bioimaging using near infrared to near infrared up-conversion in Tm3+ and Yb3+ doped fluoride nanophosphors. Nano Lett 2008, 8: 3834–3838.
Wang L, Yan R, Huo Z, et al. Fluorescence resonant energy transfer biosensor based on upconversion-luminescent nanoparticles. Angew Chem Int Edit 2005, 44: 6054–6057.
Zych E, Trojan-Piegza J, Kępiński L. Homogeneously precipitated Lu2O3:Eu nanocrystalline phosphor for X-ray detection. Sensor Actuat B: Chem 2005, 109: 112–118.
Rai VK, Pandey A, Dey R. Photoluminescence study of Y2O3:Er3+–Eu3+–Yb3+ phosphor for lighting and sensing applications. J Appl Phys 2013, 113: 083104.
Murthy KVR. Up-conversion phosphors synthesis and application in solar converters. Int J Lumin Appl 2013, 3: 1–5.
Furman JD, Warner AY, Teat SJ, et al. Tunable ligand-based emission from inorganic-organic frameworks: A new approach to phosphors for solid state lighting and other applications. Chem Mater 2010, 22: 2255–2260.
Chen Z, He S, Butt H-J, et al. Photon upconversion lithography: Patterning of biomaterials using near-infrared light. Adv Mater 2015, 27: 2203–2206.
Qiao R, Liu C, Liu M, et al. Ultrasensitive in vivo detection of primary gastric tumor and lymphatic metastasis using upconversion nanoparticles. ACS Nano 2015, 9: 2120–2129.
Yuan C, Chen G, Li L, et al. Simultaneous multiple wavelength upconversion in a core–shell nanoparticle for enhanced near infrared light harvesting in a dye-sensitized solar cell. ACS Appl Mater Interfaces 2014, 6: 18018–18025.
Ivanova S, Pellé F. Strong 1. 53 μm to NIR–VIS–UV upconversion in Er-doped fluoride glass for high-efficiency solar cells. J Opt Soc Am B 2009, 26: 1930–1938.
Liu M, Lu Y, Xie ZB, et al. Enhancing near-infrared solar cell response using upconverting transparent ceramics. Sol Energ Mat Sol C 2011, 95: 800–803.
Lahoz F, Pérez-Rodríguez C, Hernández SE, et al. Upconversion mechanisms in rare-earth doped glasses to improve the efficiency of silicon solar cells. Sol Energ Mat Sol C 2011, 95: 1671–1677.
Ma X, Peng Z, Li J. Effect of Ta2O5 Substituting on thermal and optical properties of high refractive index La2O3–Nb2O5 glass system prepared by aerodynamic levitation method. J Am Ceram Soc 2015, 98: 770–773.
Li J, Li J, Li B, et al. An upconversion niobium pentoxide bulk glass codoped with Er3+/Yb3+ fabricated by aerodynamic levitation method. J Am Ceram Soc 2015, 98: 1865–1869.
Yoshimoto K, Masuno A, Inoue H, et al. Transparent and high refractive index La2O3–WO3 glass prepared using containerless processing. J Am Ceram Soc 2012, 95: 3501–3504.
Pukhkaya V, Goldner P, Ferrier A, et al. Impact of rare earth element clusters on the excited state lifetime evolution under irradiation in oxide glasses. Opt Express 2015, 23: 3270–3281.
Li J, Ba G, Hu P, et al. Amorphous titanate nanospheres fabricated using contactless phase change process. J Mater Chem 2012, 22: 9450–9454.
Xiang H, Guan L, Peng Z, et al. Preparation of high refractive index La2O3–TiO2 glass by aerodynamic levitation technique and effects of Bi2O3 substitution on its thermal and optical properties. Ceram Int 2014, 40: 4985–4988.
Nagashio K, Takamura H, Kuribayashi K. Containerless solidification of peritectic and eutectic ceramics using aero-acoustic levitator. Mater Sci Forum 2000, 329-330: 173–17.
Liu Y, Lin H, Joanne TD, et al. Kinetics versus energetics in dye-sensitized solar cells based on an ethynyl-linked porphyrin heterodimer. J Phys Chem C 2014, 118: 1426–1435.
Zhao J. Foundation of Material Science. Dalian, China: DUT Press, 2010: 45.
Shi L, Shen Q, Qiu Z. Concentration-dependent upconversion emission in Er-doped and Er/Yb-codoped LiTaO3 polycrystals. J Lumin 2014, 148: 94–97.
Pan X, Yu J, Liu Y, et al. Thermal, mechanical, and upconversion properties of Er3+/Yb3+ co-doped titanate glass prepared by levitation method. J Alloys Compd 2011, 509: 7504–7507.
Li D, Dong B, Bai X, et al. Influence of the TGA modification on upconversion luminescence of hexagonal-phase NaYF4:Yb3+,Er3+ nanoparticles. J Phys Chem C 2010, 114: 8219–8226.
Choi DH, Kang DH, Yi SS, et al. Up-conversion luminescent properties of La(0.80-x)VO4:Ybx,Er0.20 phosphors. Mater Res Bull 2015, 71: 16–20.
Marín-Dobrincic M, Sanz-García JA, Cantelar E, et al. LiNbO3:Yb3+/Er3+/Tm3+—power driven green to blue tenability. Mater Lett 2013, 96: 63–66.
Acknowledgements
This work was financially supported by the National Natural Science Foundation of China (Grant Nos. 51671181, 51674232, and 51471158), Beijing Natural Science Foundation (No. 2152032), the Science and Technology Plan of Shenzhen City (Grant No. JCYJ20150827165038323), State Key Laboratory of New Ceramic and Fine Processing Tsinghua University (No. KF201417), the Open Funding Project of Key Laboratory of Photochemical Conversion and Optoelectronic Materials (TIPC in CAS), and the Instrument Developing Project of the Chinese Academy of Sciences (Grant No. YZ201520).
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Lia, X., Li, J., Li, J. et al. Upconversion 32Nb2O5–10La2O3–16ZrO2 glass activated with Er3+/Yb3+ and dye sensitized solar cell application. J Adv Ceram 6, 312–319 (2017). https://doi.org/10.1007/s40145-017-0243-3
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DOI: https://doi.org/10.1007/s40145-017-0243-3