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The effect of thermolysis temperatures of two silver(I) supramolecular polymers on the formation of silver nanostructures

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Abstract

Two silver(I) supramolecular polymers, [Ag(8-HqH)(8-Hq)] n (1) and {[Ag(8-HqH)2]NO3} n (2), (8-HqH = 8-hydroxyquinoline), have been synthesized and characterized by X-ray powder diffraction, IR, 1H-NMR and 13C-NMR spectroscopies. These supramolecular polymers were used as new precursors for preparation of silver nanostructures. The effect of thermolysis temperature on preparation of silver nanoparticles from these precursors was investigated. The morphology of silver nanostructure is strongly dependent on thermolysis temperature. With increase in temperature, the tendency of silver nanoparticles to agglomerate was increased.

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References

  1. S. Kitagawa, R. Kitaura, S.-I. Noro, Angew. Chem. Int. Ed. 43, 2334 (2004)

    Article  CAS  Google Scholar 

  2. R.J. Kuppler, D.J. Timmons, Q.-R. Fang, J.-R. Li, T.A. Makal, M.D. Young, D. Yuan, D. Zhao, W. Zhuang, H.-C. Zhou, Coord. Chem. Rev. 253, 3042 (2009)

    Article  CAS  Google Scholar 

  3. K. Akhbari, A. Morsali, Dalton Trans. 42, 4786 (2013)

    Article  CAS  Google Scholar 

  4. Z.-J. Li, S.K. Khani, K. Akhbari, A. Morsali, P. Retailleau, Microporous Mesoporous Mater. 199, 93 (2014)

    Article  CAS  Google Scholar 

  5. K.W. Hellmann, L.H. Gade, R. Fleischer, D. Stalke, Chem. Commun. 527 (1997)

  6. J.A. Zerowski, C.T. Seto, G.M. Whitesides, J. Am. Chem. Soc. 114, 5473 (1992)

    Article  Google Scholar 

  7. J.-M. Lehn, M. Mascal, A. DeCian, J. Fischer, J. Chem. Soc. Chem. Commun. 479 (1990)

  8. Y.-L. Chang, M.-A. West, F.W. Fowler, J.W. Lauher, J. Am. Chem. Soc. 115, 5991 (1993)

    Article  CAS  Google Scholar 

  9. E.A.H. Griffith, E.L. Amma, J. Am. Chem. Soc. 96, 743 (1974)

    Article  CAS  Google Scholar 

  10. H.G. Smith, R.E. Rundle, J. Am. Chem. Soc. 80, 5075 (1958)

    Article  CAS  Google Scholar 

  11. H. Schmidbaur, W. Bublak, B. Huber, G. Reber, G. Muller, Angew. Chem. Int. Ed. Engl. 25, 1089 (1986)

    Article  Google Scholar 

  12. G.L. Ning, L.P. Wu, K. Sugimoto, M. Munakata, T. Kuroda-Sowa, M. Mackawa, J. Chem. Soc. Dalton Trans. 2529 (1999)

  13. M. Munakata, L.P. Wu, T. Kuroda-Sowa, M. Maekawa, Y. Suenaga, G.L. Ning, T. Kojima, J. Am. Chem. Soc. 120, 8610 (1998)

    Article  CAS  Google Scholar 

  14. R. Bashiri, K. Akhbari, A. Morsali, M. Zeller, J. Organomet. Chem. 693, 1903 (2008)

    Article  CAS  Google Scholar 

  15. K. Akhbari, A. Morsali, S. Rafiei, M. Zeller, J. Organomet. Chem. 693, 257 (2008)

    Article  CAS  Google Scholar 

  16. K. Akhbari, A. Morsali, M. Zeller, J. Organomet. Chem. 692, 3788 (2007)

    Article  CAS  Google Scholar 

  17. K. Akhbari, A. Morsali, L.-G. Zhu, J. Mol. Struct. 891, 132 (2008)

    Article  CAS  Google Scholar 

  18. M. Jansen, Angew. Chem. Int. Ed. 26, 1098 (1987)

    Article  Google Scholar 

  19. C.-S. Liu, P.-Q. Chen, E.-C. Yang, J.-L. Tian, X.-H. Bu, Z.-M. Li, H.-W. Sun, Z. Lin, Inorg. Chem. 45, 5812 (2006). (and references cited therein)

    Article  CAS  Google Scholar 

  20. C.-S. Liu, P.-Q. Chen, Z. Chang, J.-J. Wang, L.-F. Yan, H.-W. Sun, X.-H. Bu, Z. Lin, Z.-M. Li, S.R. Batten, Inorg. Chem. Commun. 11, 159 (2008)

    Article  CAS  Google Scholar 

  21. C. Santini, C. Pettinari, G. Gioia Lobbia, R. Spagna, M. Pellei, F. Vallorani, Inorg. Chim. Acta 285, 81 (1999)

    Article  CAS  Google Scholar 

  22. H. Liang, Q. Tang, K. Yu, S. Li, J. Ke, Mater. Lett. 61, 1020 (2007)

    Article  CAS  Google Scholar 

  23. M.Y. Masoomi, A. Morsali, Coord. Chem. Rev. 256, 2921 (2012)

    Article  CAS  Google Scholar 

  24. R. Das, P. Pachfule, R. Banerjee, P. Poddar, Nanoscale 4, 591 (2012)

    Article  CAS  Google Scholar 

  25. M. Moeinian, K. Akhbari, J. Solid State Chem. 225, 459 (2015)

    Article  CAS  Google Scholar 

  26. F. Shahangi Shirazi, K. Akhbari, RSC Adv. 5, 50778 (2015)

    Article  Google Scholar 

  27. F. Shahangi Shirazi, K. Akhbari, Inorg. Chem. Acta. 436, 1 (2015)

    Article  CAS  Google Scholar 

  28. K. Akhbari, A. Morsali, Z. Anorg, Allg. Chem. 638, 692 (2012)

    Article  CAS  Google Scholar 

  29. K. Akhbari, A. Morsali, Cryst. Eng. Commun. 12, 3394 (2010)

    Article  CAS  Google Scholar 

  30. K. Akhbari, M. Hemmati, A. Morsali, J. Inorg. Organomet. Polym. 21, 352 (2011)

    Article  CAS  Google Scholar 

  31. K. Akhbari, A. Morsali, Inorg. Chem. Acta. 363, 1435 (2010)

    Article  CAS  Google Scholar 

  32. S. Hojaghani, K. Akhbari, M. Hossaini Sadr, A. Morsali, Inorg. Chem. Commun. 44, 1 (2014)

    Article  CAS  Google Scholar 

  33. K. Akhbari, A. Morsali, P. Retailleau, Polyhedron 29, 3304 (2010)

    Article  CAS  Google Scholar 

  34. R. Bashiri, K. Akhbari, A. Morsali, Inorg. Chem. Acta. 362, 1035 (2009)

    Article  CAS  Google Scholar 

  35. H. Wu, X.-W. Dong, H.-Y. Liu, J.-F. Ma, Acta Crystallogr. Sect. E 62, m281 (2006)

    Article  CAS  Google Scholar 

  36. K. Akhbari, A. Morsali, Inorg. Chem. 52, 2787 (2013)

    Article  CAS  Google Scholar 

  37. C.F. Macrae, P.R. Edgington, P. McCabe, E. Pidcock, G.P. Shields, R. Taylor, M. Towler, J. van de Streek, J. Appl. Cryst. 39, 453 (2006)

    Article  CAS  Google Scholar 

  38. P. Pyykkö, Chem. Rev. 97, 597 (1997)

    Article  Google Scholar 

Download references

Acknowledgments

The authors would like to acknowledge the financial support of the University of Tehran for this research under grant number 01/1/389845 and support of this investigation by Tarbiat Modares University.

Author information

Authors and Affiliations

  1. School of Chemistry, College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, Islamic Republic of Iran

    Kamran Akhbari

  2. Department of Chemistry, Shahr-E-Ray Branch, Islamic Azad University, P. O. Box 49195-467, Tehran, Islamic Republic of Iran

    Nasim Band Bahman

  3. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-4838, Tehran, Islamic Republic of Iran

    Ali Morsali

  4. Service de Cristallochimie, Institut de Chimie des Substances Naturelles-CNRS, Bât 27, 1 Avenue de la Terrasse, 91190, Gif sur Yvette, France

    Pascal Retailleau

Authors
  1. Kamran Akhbari
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  2. Nasim Band Bahman
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  3. Ali Morsali
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  4. Pascal Retailleau
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Corresponding authors

Correspondence to Kamran Akhbari or Ali Morsali.

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13738_2015_724_MOESM1_ESM.doc

Supplementary material 1 (DOC 1230 kb) Supplementary material Electronic Supplementary Information (ESI) including experimental data, IR, 1H-NMR, 13C-NMR spectra and XRD patterns are available

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Akhbari, K., Bahman, N.B., Morsali, A. et al. The effect of thermolysis temperatures of two silver(I) supramolecular polymers on the formation of silver nanostructures. J IRAN CHEM SOC 13, 165–169 (2016). https://doi.org/10.1007/s13738-015-0724-7

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  • DOI: https://doi.org/10.1007/s13738-015-0724-7

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