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Green oxidation of olefins and methyl phenyl sulfide with hydrogen peroxide catalyzed by an oxovanadium(IV) Schiff base complex encapsulated in the nanopores of zeolite-Y

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Abstract

Oxovanadium(IV) complex of a Schiff base ligand derived from 2,4-dihydroxyacetophenone and 2,2′-dimethylpropanediamine has been encapsulated in the nanopores of zeolite-Y by flexible ligand method and characterized by metal analysis, IR spectroscopic studies and X-ray diffraction patterns. The encapsulated complex [VOL-Y] catalyzes the oxidation of various olefins and methyl phenyl sulfide using hydrogen peroxide as a green oxidant in good yield. Under the optimized reaction conditions, in the presence of VOL-Y, 86 % conversion of cyclooctene with 100 % selectivity for epoxide and 51 % conversion for methyl phenyl sulfide with 92 % selectivity for sulfone were obtained.

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Acknowledgments

This work has been supported by the Iran National Science Foundation (INSF) (Grant No. 88001216).

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Authors and Affiliations

  1. Department of Chemistry, K.N. Toosi University of Technology, P.O. Box 16315-1618, 15418, Tehran, Iran

    Saeed Rayati & Fatemeh Salehi

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  1. Saeed Rayati
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  2. Fatemeh Salehi
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Correspondence to Saeed Rayati.

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Rayati, S., Salehi, F. Green oxidation of olefins and methyl phenyl sulfide with hydrogen peroxide catalyzed by an oxovanadium(IV) Schiff base complex encapsulated in the nanopores of zeolite-Y. J IRAN CHEM SOC 12, 309–315 (2015). https://doi.org/10.1007/s13738-014-0485-8

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  • DOI: https://doi.org/10.1007/s13738-014-0485-8

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