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Synthesis, crystal structure, and properties of hybrid-3D copper tetraphosphonate: [Cu3((HO3PCH2)2N–CH2C6H4CH2–N(CH2PO3H)2)(H2O)4] n

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Abstract

The new copper(II) tetraphosphonate, [Cu3(HO3PCH2)2N–CH2C6H4CH2–N(CH2PO3H)2)(H2O)4] n (1) was hydrothermally synthesized from the reaction of Cu(NO3)2 and (H2O3PCH2)2N–CH2C6H4CH2–N(CH2PO3H2)2, (H8L). Compound 1 was structurally characterized by means of X-ray single crystal diffraction. The structure of 1 showed a 3D structure constructed from two types of Cu(II) and chelating and bridging modes of (HO3PCH2)2N–CH2C6H4CH2–N(CH2PO3H)2, and features a (44.610.8) topological network. The 3D compound is further stabilized by hydrogen bonds. UV–Vis diffuse reflectance and infrared spectroscopy as well as elemental analysis of compound 1 are also presented.

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References

  1. A. Clearfield, Prog. Inorg. Chem. 47, 371 (1998)

    Article  CAS  Google Scholar 

  2. E.K. Brechin, R.A. Coxall, A. Parkin, S. Parsons, P.A. Tasker, R.E.P. Winpenny, Angew. Chem. Int. Ed. 40, 2700 (2001)

    Article  CAS  Google Scholar 

  3. G. Alberti, U. Constantino, M. Casciola, R. Vivani, Adv. Mater. 8, 291 (1996)

    Article  CAS  Google Scholar 

  4. A. Clearfield, Progress in Inorganic Chemistry: Metal–Phosphonate Chemistry (John Wiley & Sons Inc., New York, 1998)

    Google Scholar 

  5. P.M. Forster, A.K. Cheetham, Top. Catal. 24, 79 (2003)

    Article  CAS  Google Scholar 

  6. R.C. Finn, R.S. Rarig Jr, J. Zubieta, Inorg. Chem. 41, 2109 (2002)

    Article  CAS  Google Scholar 

  7. H.C. Yao, Y.Z. Li, S. Gao, Y. Song, L.M. Zheng, X.Q. Xin, J. Solid State Chem. 177, 4557 (2004)

    Article  CAS  Google Scholar 

  8. F.H. Fry, P. Jensen, C.M. Kepert, L. Spiccia, Inorg. Chem. 42, 5637 (2003)

    Article  CAS  Google Scholar 

  9. C. Serre, G. Férey, J. Mater. Chem. 12, 2367 (2002)

    Article  CAS  Google Scholar 

  10. S. Bauer, H. Müller, T. Bein, N. Stock, Inorg. Chem. 44, 9464 (2005)

    Article  CAS  Google Scholar 

  11. A. Clearfield, J. Alloys Compd. 418, 128 (2006)

    Article  CAS  Google Scholar 

  12. Y. Zhang, A. Clearfield, Inorg. Chem. 31, 2821 (1992)

    Article  CAS  Google Scholar 

  13. N. Stock, A. Stoll, T. Bein, Micropor. Mesopor. Mat. 69, 65 (2004)

    Article  CAS  Google Scholar 

  14. F. Costantino, T. Bataille, N. Audebrand, E.L. Fur, C. Sangregorio, Cryst. Growth Des. 7, 1881 (2007)

    Article  CAS  Google Scholar 

  15. A. Sonnauer, N. Stock, Eur. J. Inorg. Chem. 2008, 5038 (2008)

    Article  CAS  Google Scholar 

  16. S. Dehghanpour, S. Asadizadeh, J. Assoud, Z. Anorg, Allg. Chem. 638, 861 (2012)

    Article  CAS  Google Scholar 

  17. K. Moedritzer, R.R. Irani, J. Org. Chem. 31, 1603 (1966)

    Article  CAS  Google Scholar 

  18. SAINT PLUS, version 6.02; Bruker AXS, Inc, Madison (1999)

  19. G.M. Sheldrick, SADABS, Siemens Area Detector Absorption Correction (Universität Göttingen, Göttingen, 1996)

    Google Scholar 

  20. G.M. Sheldrick, SHELXTL, version 5.1 (Bruker AXS, Inc, Madison, 1998)

    Google Scholar 

  21. A. Cabeza, M.A.G. Aranda, S. Bruque, J. Mater. Chem. 9, 571 (1999)

    Article  CAS  Google Scholar 

  22. H.S. Martinez-Tapia, A. Cabeza, S. Bruque, P. Pertierra, S. Garcia-Granda, M.A.G. Aranda, J. Solid State Chem. 151, 122 (2000)

    Article  CAS  Google Scholar 

  23. K.L. Nash, R.D. Rogers, J. Ferraro, J. Zhang, Inorg. Chim. Acta 269, 211 (1998)

    Article  CAS  Google Scholar 

  24. C. Bellitto, F. Federici, Inorg. Chem. 41, 709 (2002)

    Article  CAS  Google Scholar 

  25. B.P. Yang, A.V. Prosvirinb, H–.H. Zhaob, J.G. Mao, J. Solid State Chem. 179, 175 (2006)

    Article  CAS  Google Scholar 

  26. B. Zurowska, A. Brzuszkiewicz, J. Ochocki, Polyhedron 27, 1721 (2008)

    Article  CAS  Google Scholar 

  27. J. Perez, L. Garcya, M. Kessler, K. Nolsoe, E. Perez, J.L. Serrano, J.F. Martynez, R. Carrascosa, Inorg. Chim. Acta 358, 2432 (2005)

    Article  CAS  Google Scholar 

  28. G. Yucesan, W. Ouellette, Y.H. Chuang, J. Zubieta, Inorg. Chim. Acta 360, 1502 (2007)

    Article  CAS  Google Scholar 

  29. R. Murugavel, S. Kuppuswamy, A.N. Maity, M.P. Singh, Inorg. Chem. 48, 183 (2009)

    Article  CAS  Google Scholar 

  30. G. Lia, Y. Fana, T. Zhanga, T. Gea, H. Houa, J. Coord. Chem. 61, 540 (2008)

    Article  CAS  Google Scholar 

  31. A.M. Herrera, R.J. Staples, S.V. Kryatov, A.Y. Nazarenko, E.V. Rybak-Akimova, Dalton Trans. 5, 846 (2003)

    Article  CAS  Google Scholar 

  32. A.L. Spek, J. Applied Crystallography 36, 7 (2003)

    Article  CAS  Google Scholar 

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Acknowledgments

Financial support by the Alzahra University is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Alzahra University, P.O. Box 1993891176, Tehran, Iran

    Saeed Dehghanpour, Maryam Rezazadeh & Khadijeh Jahani

  2. Department of Chemistry, Islamic Azad University, Karaj Branch, Karaj, Iran

    Ali Mahmoudi & Mehdi Khalaj

  3. Department of Mechanical Engineering, University of Alberta, Edmonton, AB, Canada

    Amir H. Mahmoudkhani

Authors
  1. Saeed Dehghanpour
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  2. Maryam Rezazadeh
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  3. Ali Mahmoudi
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  4. Amir H. Mahmoudkhani
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  5. Mehdi Khalaj
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  6. Khadijeh Jahani
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Correspondence to Saeed Dehghanpour.

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Dehghanpour, S., Rezazadeh, M., Mahmoudi, A. et al. Synthesis, crystal structure, and properties of hybrid-3D copper tetraphosphonate: [Cu3((HO3PCH2)2N–CH2C6H4CH2–N(CH2PO3H)2)(H2O)4] n . J IRAN CHEM SOC 11, 751–757 (2014). https://doi.org/10.1007/s13738-013-0348-8

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