Abstract
A new field-assisted annealing approach for Cu-Zr alloy metallization is proposed and investigated. Cu-Zr/SiO2/Si samples were vacuum-annealed at pressure of 2 × 10−3 Pa with (−20 V) and without field-assisted annealing for an hour in 250°C–400°C temperature range. Based on the XRD, TEM, XPS, and resistivity measurement results, we conclude that the dragging force for Zr atoms in field-assisted annealing samples to the interface shall be larger than that of samples without field-assisted annealing. As a consequence, by low concentration alloy atoms adding and FAA processing, the low Cu alloy film resistivity and thin self-forming barrier layer can be simultaneously obtained at lower temperature.
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Wang, Y., Cao, F. & Zhang, Ml. A new field-assisted annealing approach for advanced Cu-Zr Alloy metallization. Electron. Mater. Lett. 8, 507–510 (2012). https://doi.org/10.1007/s13391-012-2065-3
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DOI: https://doi.org/10.1007/s13391-012-2065-3