Abstract
A nonlinear model representing particle diffusion and molecular diffusion is considered in this paper. The equations are converted into dimensionless form involving Peclet and Biot numbers. The model is discretized in axial and radial domains using a cubic spline collocation method. The system of differential algebraic equations is obtained and is solved using MATLAB ODE15s. Using the actual plant data, the results are examined in terms of relative error. A uniform convergence of order two is established. Also, the model is simulated to study the effect of different parameters on exit solute concentration.
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Abbreviations
- B :
-
Permeability coefficient (m2)
- c :
-
Solute concentration in the fluid (kg/m3)
- C F :
-
Consistency of fibers (kg/m3)
- C 0 :
-
Concentration of solute inside the vat (kg/m3)
- D F :
-
Intrafiber diffusion coefficient (m2/s)
- D L :
-
Longitudinal dispersion coefficient (m2/s)
- K :
-
Dimensionless volumetric equilibrium constant
- k f :
-
Film mass transfer coefficient (m/s)
- k 1, k 2 :
-
Mass transfer coefficients (1/s)
- L :
-
Thickness of packed bed (m)
- n :
-
Solute concentration adsorbed on the fibers (kg/kg)
- N 0 :
-
Initial concentration of solute adsorbed on the fibers (kg/kg)
- q :
-
Concentration of solute inside the pores (kg/m3)
- r :
-
Radial position solute in particle (m)
- R :
-
Fiber radius (m)
- Re :
-
Reynolds number, (= 4ru ρ/μ), dimensionless
- t :
-
Time (s)
- u :
-
Interstitial velocity of liquor through the bed (m/s)
- z :
-
Variable thickness of packed bed (m)
- ω :
-
Porosity of the particle
- ɛ :
-
Porosity of the cake
- μ :
-
Liquid viscosity (Pa s)
- ρ :
-
Liquid density (kg/m3)
References
Brenner H.: The diffusion model of longitudinal mixing in beds of finite length. Numerical values. Chem. Eng. Sci. 17, 229–243 (1962)
Sherman W.R.: The movement of a soluble material during the washing of a bed of packed solids. AIChE 10(6), 855–860 (1964)
Neretnieks I.: A mathematical model for continuous counter current adsorption. Svensk Papperstidning 11, 407–411 (1974)
Pellett G.L.: Longitudinal dispersion, intraparticle diffusion, and liquid-phase mass transfer during flow through multiparticle systems. Tappi 49(2), 75–82 (1966)
Grahs, L.E.: Washing of cellulose fibres, analysis of displacement washing operation. Ph.D. Thesis. Chalmers University of Technology, Goteborg, Sweden (1974)
Cocero M.J., Garcia J.: Mathematical model of supercritical extraction applied to oil seed extraction by CO2 + saturated alcohol—I. Desorption model. J. Supercrit. Fluids 20, 229–243 (2001)
Liu F., Bhatia S.K.: Computationally efficient solution techniques for adsorption problems involving steep gradients bidisperse particles. Comput. Chem. Eng. 23, 933–943 (1999)
Raghvan N.S., Ruthven D.M.: Numerical simulation of a fixed bed adsorption column by the method of orthogonal collocation. AIChE 29(6), 922–925 (1983)
Al-Jabari M., Van Heiningen A.R.P., Van De Ven T.G.M.: Modeling the flow and the deposition of fillers in packed bed of pulp fibers. J. Pulp Pap. Sci. 20(9), J249–J253 (1994)
Sridhar P., Sastri N.V.S., Modak J.M., Mukherjee A.K.: Mathematical simulation of bioseparation in an affinity packed column. Chem. Eng. Technol. 17, 422–429 (1994)
Potůček F.: Chemical engineering view of pulp washing. Papir a celulóza 60(4), 114–117 (2005)
Potůček F.: Displacement washing of pulp I. Dispersion model for non ideal flow. Papir a celulóza 56(1), 8–11 (2001)
Potůček F.: Washing of pulp fiber bed. Collect. Czech. Chem. Commun. 62, 626–644 (1997)
Kill S., Bhatia S.K.: Solution of adsorption problems involving steep moving profiles. Comput. Chem. Eng. 22(7–8), 893–896 (1998)
Saritha N.V., Madras G.: Modeling the chromatographic response of inverse size-exclusion chromatography. Chem. Eng. Sci. 56, 6511–6524 (2001)
Farooq S., Karimi I.A.: Dispersed plug flow model for steady state laminar flow in a tube with a first order sink at the wall. Chem. Eng. Sci. 58, 71–80 (2003)
Arora S., Dhaliwal S.S., Kukreja V.K.: Simulation of washing of packed bed of porous particles by orthogonal collocation on finite elements. Comput. Chem. Eng. 30, 1054–1060 (2006)
Arora S., Potůček F.: Modelling of displacement of washing of pulp: comparison between model and experimental data. Cell Chem. Technol. 43(7–8), 307–315 (2009)
Ahmed S.G.: A numerical algorithm for solving advection–diffusion equation with constant and variable coefficients. Open Numer. Methods. J. 4, 1–7 (2012)
Guraslan G., Sari M.: Numerical solutions of linear and nonlinear diffusion equations by a differential quadrature method. Int. J. Numer. Methods Biomed. Eng. 27, 69–77 (2011)
Hasson D., Drak A., Yang Q., Semiat R.: Effect of axial dispersion on the concentration polarization level in spiral wound modules. Desalination 199, 451–453 (2006)
Kar M., Sahoo S.N., Rath P.K., Dash G.C.: Heat and mass transfer effects on a dissipative and radiative visco-elastic MHD flow over a stretching porous sheet. AJSE 39(05), 3393–3401 (2014)
Mohebbi A., Dehghan M.: High-order compact solution of the one-dimensional heat and advection–diffusion equations. Appl. Math. Model. 34, 3071–3084 (2010)
Okhovat A., Heris S.Z., Asgarkhani M.A.H., Fard K.M.: Modeling and simulation of erosion–corrosion in disturbed two-phase flow through fluid transport pipelines. AJSE 39(03), 1497–1505 (2014)
Roininen J., Alopaeus V.: The moment method for one-dimensional dynamic reactor models with axial dispersion. Comput. Chem. Eng. 35, 423–433 (2011)
de Boor C., Swartz B.: Collocation at Gaussian points. SIAM J. Numer. Anal. 10, 582–606 (1973)
Botella O.: On a B-spline Collocation method for the solution of the Navier–Stokes equations. Comput. Fluids 31, 397–420 (2001)
Fairweather G., Meade D.: A survey of spline collocation methods for the numerical solution of differential equations. Math. Large Scale Comput. 120, 297–341 (1989)
Gupta B., Kukreja V.K.: Numerical approach for solving diffusion problems using cubic B-spline collocation method. Appl. Math. Comput. 219, 2087–2099 (2012)
Johnson R.W.: Higher order B-spline collocation at the Greville abscissae. Appl. Numer. Math. 52, 63–75 (2005)
Mazzia F., Sestini A., Trigiante D.: B-spline linear multistep methods and their continuous extensions. SIAM J. Numer. Anal. 44, 1954–1973 (2006)
Saka B., Dağ I.: A numerical study of the Burgers’ equation. J. Frankl. Inst. 345, 328–348 (2008)
Arora S., Potůček F.: Verification of mathematical model fro displacement washing of kraft pulp fibers. Indian J. Chem. Technol. 19, 140–148 (2012)
de Boor C.: A Practical Guide to Splines. Springer, New York (1978)
Prenter P.M.: Splines and Variational Methods. Wiley Interscience Publication, New York (1975)
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Gupta, B., Kukreja, V.K., Parumasur, N. et al. Numerical Study of a Nonlinear Diffusion Model for Washing of Packed Bed of Cylindrical Fiber Particles. Arab J Sci Eng 40, 1279–1287 (2015). https://doi.org/10.1007/s13369-015-1633-x
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DOI: https://doi.org/10.1007/s13369-015-1633-x