Abstract
Oxygen and carbon dioxide sensors are involved in many chemical and biochemical reactions. Consequently, considerable efforts over years have been devoted to discover and improve suitable techniques for measuring gas concentrations by optical fiber sensors. Optical gas sensors consist of a gas-sensitive dye entrapped in a matrix with a high permeability to gas. With such sensors, gas concentration is evaluated based upon the reduction in luminescence intensity caused by gas quenching of the emitting state. However, the luminescence quenching effect of oxygen is highly sensitive to temperature. Thus, a simple, low-cost plastic optical fiber sensor for dual sensing of temperature and oxygen is presented. Also, a modified Stern-Volmer model is introduced to compensate for the temperature drift while the temperature is obtained by above dual sensor. Recently, we presented highly-sensitive oxygen and dissolved oxygen sensors comprising an optical fiber coated at one end with platinum (II) meso-tetrakis(pentafluorophenyl)porphyrin (PtTFPP) and PtTFPP entrapped core-shell silica nanoparticles embedded in an n-octyltriethoxysilane(Octyl-triEOS)/tetraethylorthosilane (TEOS) composite xerogel. Also, two-dimensional gas measurement for the distribution of chemical parameters in non-homogeneous samples is developed and is of interest in medical and biological researches.
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J. N. Demas, B. A. Degraff, and P. B. Coleman, “Oxygen sensors based on luminescence quenching,” Anal. Chem., vol. 71, no. 23, pp. 793A–800A, 1999.
K. Tsukada, S. Sakai, K. Hase, and H. Minamitani, “Development of catheter type optical oxygen sensor and applications to bioinstrumentation,” Biosens. Bioelectron., vol. 18, no. 12, pp. 1439–1445, 2003.
E. VanderDonckt, B. Camerman, R. Herne, and R. Vandeloise, “Fiber-optic oxygen sensor based on luminescence quenching of a Pt(II) complex embedded in polymer matrices,” Sens. Actuators B Chem., vol. 32, no. 3, pp. 121–127, 1996.
P. Douglas and K. Eaton, “Response characteristics of thin film oxygen sensors, Pt and Pd octaethylporphyrins in polymer films,” Sens. Actuators B Chem., vol. 82, no. 2–3, pp. 200–208, 2002.
C. McDonagh, B. D. MacCraith, and A. K. McEcoy, “Tailoring of sol-gel films for optical sensing of oxygen in gas and aqueous phase,” Anal. Chem., vol. 70, no. 1, pp. 45–50, 1998.
Y. Tang, E. C. Tehan, Z. Tao, and F. V. “Bright, sol-gel-derived sensor materials that yield linear calibration plots, high sensitivity, and long-term stability,” Anal. Chem., vol. 75, no. 10, pp. 2407–2413, 2003.
R. M. Bukowski, R. Ciriminna, M. Pagliaro, and F. V. Bright, “High-performance quenchometric oxygen sensors based on fluorinated xerogels doped with [Ru(dpp)(3)](2+),” Anal. Chem., vol. 77, no. 8, pp. 2670–2672, 2005.
T. J. Manuccia and J. G. Eden, “Infrared optical measurement of blood gas concentrations and fiber optic catheter,” U.S., Patent 4,509,522, 1985.
B. H. Weigl and O. S. Wolfbeis, “Capillary optical sensors,” Anal. Chem., vol. 66, no. 20, pp. 3323–3327, 1994.
D. A. Nivens, M. V. Schiza, and S. M. Angel, “Multilayer sol-gel membranes for optical sensing applications: single layer pH and dual layer CO2 and NH3 sensors,” Talanta, vol. 58, no. 3, pp. 543–550, 2002.
A. Mills and Q. Chang, “Fluorescence plastic thin-film sensor for carbon dioxide,” Analyst, vol. 118, no. 7, pp. 839–843, 1993.
C. von Bultzingslowen, A. K. McEvoy, C. McDonagh, and B. D. MacCraith, “Lifetime-based optical sensor for high-level pCO2 detection employing fluorescence resonance energy transfer,” Anal. Chim. Acta, vol. 480, no. 2, pp. 275–283, 2003.
C. von Bultzingslowen, A. K. McEvoy, C. McDonagh, B. D. MacCraith, I. Kliment, C. Krause, and O. S. Wolfbeis, “Sol-gel based optical carbon dioxide sensor employing dual luminophore referencing for application in food packaging technology,” Analyst, vol. 127, no. 11, pp. 1478–1483, 2002.
X. He and G. A. Rechnitz, “Linear response function for fluorescence-based fiber-optic CO2 sensors,” Anal. Chem., vol. 67, no. 13, pp. 2264–2268, 1995.
C. Malins and B. D. MacCraith, “Dye-doped organically modified silica glass for fluorescence based carbon dioxide gas detection,” Analyst, vol. 123, no.11, pp. 2373–2376, 1998.
T. S. Yeh, C. S. Chu, and Y. L. Lo, “Highly sensitive optical fiber oxygen sensor using Pt(II) complex embedded in sol-gel matrices,” Sens. Actuators B Chem., vol. 119, no. 2, pp. 701–707, 2006.
C. S. Chu and Y. L. Lo, “High-performance fiber-optic oxygen sensors based on fluorinated xerogels doped with Pt(II) complexes,” Sens. Actuators B Chem., vol. 124, no. 2, pp. 376–382, 2007.
Y. Tang, E. C. Tehan, Z. Tao, and F. V. Bright, “Sol-gel-derived sensor materials that yield linear calibration plots, high sensitivity, and long-term stability,” Anal. Chem., vol. 75, no. 10, pp. 2407–2413, 2003.
K. Kalyanasundaram, “Photophysics, photochemistry and solar energy conversion with tris(bipyridyl) ruthenium(II) and its analogues,” Coord. Chem. Rev., vol. 46, no. 1–2, pp. 159–244, 1982.
C. S. Chu and Y. L. Lo, “Ratiometric fiber-optic oxygen sensors based on sol-gel matrix doped with metalloporphyrin and 7-amino-4-trifluoromethyl coumarin,” Sens. Actuators B Chem., vol. 134, no. 2, pp. 711–717, 2008.
X. Y. Wang, C. Drew, S. H. Lee, K. J. Senecal, J. Kumar, and L. A. Sarnuelson, “Electrospun nanofibrous membranes for highly sensitive optical sensors,” Nano Lett., vol. 2, no. 11, pp. 1273–1275, 2002.
S. Santra, K. M. Wang, R. Tapec, and W. H. Tan, “Development of novel dye-doped silica nanoparticles for biomarker application,” J. Biomed. Opt., vol. 6, no. 2, pp. 160–166, 2001.
C. Barbe, J. Bartlett, L. G. kong, K. Finnie, H. Q. Lin, M. Larkin, S. Calleja, A. Bush, and G. Calleja, “Silica particles: a novel drug-delivery system,” Adv. Mater., vol. 16, no. 21, pp. 1959–1966, 2004.
B. H. Han, I. Manners, and M. A. Winnik, “Oxygen sensors based on mesoporous silica particles on layer-by-layer self-assembled films,” Chem. Mater., vol. 17, no. 12, pp. 3160–3171, 2005.
C. S. Chu, Y. L. Lo, and T. W. Sung, “Enhanced oxygen sensing properties of Pt(II) complex and dye entrapped core-shell nanoparticles embedded in sol-gel matrix,” Talanta, vol. 82, no. 3, pp. 1044–1051, 2005.
Y. Amao, T. Miyashita, and I. Okura, “Platinum tetrakis (pentafluorophenyl) porphyrin immobilized in polytrifluoroethylmethacrylate film as a photostable optical oxygen detection material,” J. Fluor. Chem., vol. 107, no. 1, pp. 101–106, 2001.
S. K. Lee and I. Okura, “Photostable optical oxygen sensing material: Platinum tetrakis (pentafluorophenyl) porphyrin immobilized in polystyrene,” Anal. Comm., vol. 34, no. 6, pp. 185–188, 1997.
B. J. Basu, “Optical oxygen sensing based on luminescence quenching of platinum porphyrin dyes doped in ormosil coatings,” Sens. Actuators B Chem., vol. 123, no. 1, pp. 568–577, 2007.
A. N. Watkins, B. R. Wenner, J. D. Jordan, W. Xu, J. N. Demas, and F. V. Bright, “Portable, low-cost, solid-state luminescence-based O2 sensor,” Appl. Spectrosc., vol. 52, no. 5, pp. 750–754, 1998.
C. S. Chu and Y. L. Lo, “Optical fiber dissolved oxygen sensor based on Pt(II) complex and core-shell silica nanoparticles incorporated with sol-gel matrix,” Sens. Actuators B Chem., vol. 151, no. 1, pp. 83–89, 2010.
R. N. Gillanders, M. C. Tedford, P. J. Crilly, and R. T. Bailey, “Thin film dissolved oxygen sensor based on platinum octaethylporphyrin encapsulated in an elastic fluorinated polymer,” Anal. Chim. Acta, vol. 502, no. 1, pp. 1–6, 2004.
R. N. Gillander, M. C. Tedford, P. J. Crilly, and R. T. Bailey, “A composite thin film optical sensor for dissolved oxygen in contaminated aqueous environments,” Anal. Chim. Acta, vol. 545, no. 2, pp. 189–195, 2005.
A. K. McEvoy, C. M. McDonagh, and B. D. MacCraith, “Dissolved oxygen sensor based on fluorescence quenching of oxygen-sensitive ruthenium complexes immobilized in sol-gel-derived porous silica coatings,” Analyst, vol. 121, no. 6, pp. 785–788, 1996.
X. Chen, Z. M. Zhong, Y. Q. Jiang, X. R. Wang, and K. Y. Wong, “Characterization of ormosil film for dissolved oxygen-sensing,” Sens. Actuators B Chem., vol. 124, no. 2, pp. 233–238, 2002.
Z. Y. Tao, E. C. Tehan, Y. Tang, and F. V. Bright, “Stable sensors with tunable sensitivities based on class II xerogels,” Anal. Chem., vol. 78, no. 6, pp. 1939–1945, 2006.
X. L. Xiong, D. Xiao, and M. M. F. Choi, “Dissolved oxygen sensor based on fluorescence quenching of oxygen sensitive ruthenium complex immobilized on silica-Ni-P composite coating,” Sens. Actuators B Chem., vol. 117, no. 1, pp. 172–176, 2006.
H. L. Pang, N. Y. Kwok, L. M. C. Chow, C. H. Yeung, K. Y. Wong, X. Chen, and X. R. Wang, “ORMOSIL oxygen sensors on polystyrene microplate for dissolved oxygen measurement,” Sens. Actuators B Chem., vol. 123, no. 1, pp. 120–126, 2007.
F. H. Chu, J. J. Yang, H. W. Cai, R. H. Qu, and Z. J. Fang, “Characterization of a dissolved oxygen sensor made of plastic optical fiber coated with ruthenium-incorporated solgel,” Appl. Optics, vol. 48, no. 2, pp. 338–342, 2009.
Y. L. Lo, C. S. Chu, J. P. Yur, and Y. C. Chang, “Temperature compensation of fluorescence intensity-based fiber-optic oxygen sensors using modified Stern-Volmer model,” Sens. Actuators B Chem., vol. 131, no. 2, pp. 479–488, 2008.
S. Nagl and O. S. Wolfbeis, “Optical multiple chemical sensing: status and current challenges,” Analyst, vol. 132, no. 6, pp. 507–511, 2007.
S. M. Borisov and O. S. Wolfbeis, “Temperature-sensitive europium(III) probes and their use for simultaneous luminescent sensing of temperature and oxygen,” Anal. Chem., vol. 78, no. 14, pp. 5094–5010, 2006.
C. S. Chu and Y. L. Lo, “A plastic optical fiber sensor for the dual sensing of temperature and oxygen,” IEEE Photon. Technol. Lett., vol. 20, no. 1, pp. 63–65, 2008.
P. Hartmann, W. Ziegler, G. Holst, and D. W. Lubbers, “Oxygen flux fluorescence lifetime imaging,” Sens. Actuators B Chem., vol. 38, no. 1, pp. 110–115, 1997.
G. Holst and O. Kohls, “A modular luminescence lifetime imaging system for mapping oxygen distribution in biological samples,” Sens. Actuators B Chem., vol. 51, no. 1–3, pp. 163–170, 1998.
G. Holst and B. Grumwald, “Luminescence lifetime imaging with transparent oxygen optodes,” Sens. Actuators B Chem., vol. 74, no. 1, pp. 78–90, 2001.
T. Vo-Dinh, Biomedical Photonics Handbook. Boca Raton: CRC Press, 2003.
C. S. Chu and Y. L. Lo, “2D full-field measurement of oxygen concentration based on the phase fluorometry technique that uses the four-frame integrating bucket method,” Sens. Actuators B Chem., vol. 147, no. 1, pp. 310–315, 2010.
T. J. Manuccia and J. G. Eden, “Infrared optical measurement of blood gas concentrations and fiber optic catheter,” U.S., Patent 4,509,522, 1985.
Y. Shimizu and N. Yamashita, “Solid electrolyte CO2 sensor using NASICON and perovskite-type oxide electrode,” Sens. Actuators B Chem., vol. 64, no. 1, pp. 102–106, 2004.
Y. Amao and N. Nakamura, “An optical sensor with the combination of colorimetric change of α-naphtholphthalein and internal reference luminescent dye for CO2 in water,” Sens. Actuators B Chem., vol. 107, no. 2, pp. 861–865, 2005.
B. H. Weigl and O. S. Wolfbeis, “New hydrophobic materials for optical carbon dioxide sensors based on ion-pairing,” Anal. Chim. Acta, vol. 302, no. 2, pp. 249–254, 1995.
O. S. Wolfbeis, B. Kovacs, K. Goswami, and S. M. Klainer, “Fiber-optic fluorescence carbon dioxide sensor for environmental monitoring,” Mikrochim. Acta, vol. 129, no. 3, pp. 181–188, 1998.
G. Neurauter, I. Klimant, and O. S. Wolfbeis, “Fiber-optic microsensor for high resolution pCO2 sensing in marine environment,” Fresenius J. Anal. Chem., vol. 366, no. 5, pp. 481–487, 2000.
K. Ertekin, I. Klimant, G. Neurauter, and O. S. Wolfbeis, “Characterization of a reservoir-type capillary optical microsensor for pCO2 measurements,” Talanta, vol. 59, no. 2, pp. 261–267, 2003.
Y. Amao and N. Nakamura, “Optical CO2 sensor with the combination of colorimetric change of α-naphtholphthalein and internal reference fluorescent porphyrin,” Sens. Actuators B Chem., vol. 100, no. 3, pp. 347–351, 2004.
C. S. Chu and Y. L. Lo, “Fiber-optic carbon dioxide sensor base on fluorinated xerogels doped with HPTS,” Sens. Actuators B Chem., vol. 129, no. 1, pp. 120–125, 2008.
C. S. Chu and Y. L. Lo, “Highly sensitive and linear optical fiber carbon dioxide sensor based on sol gel matrix doped with silica particles and HPTS,” Sens. Actuators B Chem., vol. 143, no. 1, pp. 205–210, 2009.
O. Oter, K. Ertekin, and S. Derinkuyu, “Ratiometric sensing of CO2 in ionic liquid modified ethyl cellulose matrix,” Talanta, vol. 76, no. 3, pp. 557–563, 2008.
O. S. Wolfbeis and L. J. Weis, “Fiber-optic fluorosensor for oxygen and carbon dioxide,” Anal. Chem., vol. 60, no. 19, pp. 2028–2030, 1988.
O. Oter, K. Ertekin, D. Topkaya, and S. Alp, “Emission-based optical carbon dioxide sensing with HPTS in green chemistry reagents: room-temperature ionic liquids,” Anal. Bioanal. Chem., vol. 386, no. 5, pp. 1225–1234, 2006.
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Chu, CS., Lo, YL. & Sung, TW. Review on recent developments of fluorescent oxygen and carbon dioxide optical fiber sensors. Photonic Sens 1, 234–250 (2011). https://doi.org/10.1007/s13320-011-0025-4
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DOI: https://doi.org/10.1007/s13320-011-0025-4