Skip to main content
SpringerLink
Log in

Structural Effect of Ionic Liquid on Long-Term Stability in Poly(ethylene oxide)/Ag Ions/Ag Nanoparticles Composite for Olefin Separation

  • Article
  • Published:
Macromolecular Research Aims and scope Submit manuscript

Abstract

In this study, the effect of ionic liquid cation on the long-term stability of membranes was investigated using 1-methyl-3-octylimidazolium tetrafluoroborate (MOIM+BF4-). The initial permeance of the poly(ethylene oxide) (PEO)/AgBF4/MOIM+BF4-membrane was 17 gas permeation unit (GPU), but after 100 hours of gas permeation experiment, it showed a low permeance of 5.3 GPU. Uv-vis spectra also showed that MOIM+BF4- could not prevent aggregation of silver nanoparticles. This indicated that the MOIM+BF4- in the membrane could not stabilize the silver nanoparticles and thus the silver nanoparticles were aggregated and acted as a gas permeation barrier. MOIM+BF4- could not stabilize the surface of silver nanoparticles because of the long chain length of the cation. This indicated that the cation of the ionic liquid, especially carbon length, was main factor affecting the stability of separation performance with time for polymer/silver salt/ionic liquid complex membranes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. T. Yang and E. S. Kikkinides, AIChE. J., 41, 509 (1995).

    Article  CAS  Google Scholar 

  2. G. Chang, M. Huang, Y. Su, H. Xing, B. Su, Z. Zhang, Q. Yang, Y. Yang, Q. Ren, and Z. Bao, Chem. Commun., 51, 2859 (2015).

    Article  CAS  Google Scholar 

  3. M. R. A. Hamid and H.-K. Jeong, Korean J. Chem. Eng., 35, 1577 (2018).

    Article  CAS  Google Scholar 

  4. J. Park, S.-P. Kang, and J.-W. Lee, Korean J. Chem. Eng., 33, 2186 (2016).

    Article  CAS  Google Scholar 

  5. T. C. Merkell, B. D. Freeman, R. J. Spontak, Z. He, I. Pinnau, P. Meakin, and A. J. Hill, Science, 296, 519 (2002).

    Article  Google Scholar 

  6. Y. C. Hudiono, T. K. Carlisle, A. L. LaFrate, D. L. Gina, and R. D. Noble, J. Membr. Sci., 370, 141 (2001).

    Article  Google Scholar 

  7. M. H. Nematollahi, A. H. S. Dehaghani, V. Pirouzfar, and E. Akhondi, Macromol. Res., 24, 782 (2016).

    Article  CAS  Google Scholar 

  8. S. H. Kunjattu, V. Ashok, A. Bhaskar, K. Pandare, R. Banerjee, and U. K. Kharul, J. Membr. Sci., 549, 38 (2018).

    Article  CAS  Google Scholar 

  9. Y. S. Park, C. Ha, and S. W. Kang, RSC Adv., 7, 33568 (2017).

    Article  CAS  Google Scholar 

  10. I. S. Chae, S. W. Kang, and Y. S. Kang, RSC Adv., 4, 30156 (2014).

    Article  CAS  Google Scholar 

  11. J. H. Oh, Y. S. Kang, and S. W. Kang, Chem. Commun., 49, 10181 (2013).

    Article  CAS  Google Scholar 

  12. C. H. Park, J. H. Lee, J. P. Jung, and J. H. Kim, J. Membr. Sci., 533, 48 (2017).

    Article  CAS  Google Scholar 

  13. B. Jose, J. H. Ryu, B. G. Lee, H. Lee, Y. S. Kang, and H. S. Kim, Chem. Commun., 20, 2046 (2001).

    Article  Google Scholar 

  14. H. H. Huang, X. P. Ni, G. L. Loy, C. H. Chew, K. L. Tan, F. C. Loh, J. F. Deng, and G. Q. Xu, Langmuir, 12, 909 (1996).

    Article  CAS  Google Scholar 

  15. I. Pastoriza-Santos and L. M. Liz-Marźan, Langmuir, 15, 948 (1999).

    Article  CAS  Google Scholar 

  16. S. H. Mun, S. W. Kang, J. C. Cho, S. K. Koh, and Y. S. Kang, J. Membr. Sci., 332, 1 (2009).

    Article  CAS  Google Scholar 

  17. S. U. Hong, J. H. Jin, J. Won, and Y. S. Kang, Adv. Mater., 12, 968 (2000).

    Article  CAS  Google Scholar 

  18. L. Dong, J. Xie, G. Fan, Y. Huang, J. Zhou, Q. Sun, L. Wang, Z. Guan, D. Jiang, and Y. Wang, Korean J. Chem. Eng., 34, 2861 (2017).

    Article  CAS  Google Scholar 

  19. D. Kumar and N. Talreja, Korean J. Chem. Eng., 36, 126 (2019).

    Article  CAS  Google Scholar 

  20. M. Christwardana, Y. Chung, D. C. Tannia, and Y. Kwon, Korean J. Chem. Eng., 35, 2421 (2018).

    Article  CAS  Google Scholar 

  21. R. Atchudan, B. G. Cha, N. Lone, J. Kim, and J. Joo, Korean J. Chem. Eng., 36, 157 (2019).

    Article  CAS  Google Scholar 

  22. B. Pejjai, V. R. M. Reddy, K. Seku, H. Cho, M. R. Pallavolu, T. T. T. Le, D. Jeong, T. R. R. Kotte, and C. Park, Korean J. Chem. Eng., 35, 2430 (2018).

    Article  CAS  Google Scholar 

  23. M. Shahid, Z. H. Farooqi, R. Begum, K. Naseem, M. Ajmal, and A. Irfan, Korean J. Chem. Eng., 35, 1099 (2018).

    Article  CAS  Google Scholar 

  24. Y. Sun and Y. Xia, Science, 298, 2176 (2002).

    Article  CAS  Google Scholar 

  25. I. S. Chae, S. W. Kang, J. Y. Park, Y. G. Lee, J. H. Lee, J. Won, and Y. S. Kang, Angew. Chem. Int. Ed., 50, 2982 (2011).

    Article  CAS  Google Scholar 

  26. S. W. Kang, K. Char, and Y. S. Kang, Chem. Mater., 20, 1308 (2008).

    Article  CAS  Google Scholar 

  27. H. Jeon and S. W. Kang, Polym. Compos., 40, 2745 (2019).

    Article  CAS  Google Scholar 

  28. S. W. Kang and Y. S. Kang, J. Colloid Interface Sci., 353, 83 (2011).

    Article  CAS  Google Scholar 

  29. S. W. Kang, D. H. Lee, J. H. Park, K. Char, J. H. Kim, J. Won, and Y. S. Kang, J. Membr. Sci., 322, 281 (2008).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Sangmyung University, Seoul, 03016, Korea

    Hyunsik Jeon & Sang Wook Kang

  2. Department of Energy Systems Engineering, Soonchunhyang University, Asan, 31538, Korea

    Younghyun Cho

  3. Department of Chemistry and Energy Engineering, Sangmyung University, Seoul, 03016, Korea

    Sang Wook Kang

Authors
  1. Hyunsik Jeon
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Younghyun Cho
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sang Wook Kang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Younghyun Cho or Sang Wook Kang.

Additional information

Publisher’s Note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Acknowledgments: This work was supported by the Basic Science Research Program (2017R1D1A1B03032583) through the National Research Foundation of Korea (NRF), funded by the Ministry of Science, ICT, and Future Planning. This work was also supported by the Soon-chunhyang University Research Fund.

The image from this article is used as the cover image of the Volume 28, Issue 5.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jeon, H., Cho, Y. & Kang, S.W. Structural Effect of Ionic Liquid on Long-Term Stability in Poly(ethylene oxide)/Ag Ions/Ag Nanoparticles Composite for Olefin Separation. Macromol. Res. 28, 445–449 (2020). https://doi.org/10.1007/s13233-020-8057-5

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13233-020-8057-5

Keywords

Search

Navigation