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The effect of H2O2/Fe2+ catalytic oxidation system on the morphology, structure and properties of flake-like poly(2,3-dimethylaniline)

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Abstract

In this work, flake-like poly(2,3-dimethylaniline) (P(2,3-DMA)) with enhanced thermal stability and anticorrosive ability was synthesized by in situ polymerization using H2O2/Fe2+ catalytic oxidation system, comparing with traditional oxidant ammonium persulfate (APS) synthetic method. The structure and morphology of the samples were characterized Fourier transform infrared (FTIR) spectra, X-ray diffraction (XRD) and field-emission scanning electron microscope (FESEM). The experimental results demonstrated that using H2O2/Fe2+ catalytic oxidation system was more inclined to form the two-dimensional P(2,3-DMA) flakes. The enhancement in thermostability and corrosion resistance was attributed to the formation of phenazine-like structures in the polymer chains, which could serve as templates to form the flake-like morphology. In addition, using H2O2/Fe2+ catalytic oxidation system is more environmental friendly than the APS method that can avoid ammonium pollution on aquatic life as well as waters.

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Authors and Affiliations

  1. College of Chemistry & Chemical Engineering, Chongqing University, Chongqing, 400030, P. R. China

    Jun Yan, Li Ma, Mengyu Gan, Xiao Li, Zhitao Li, Jihai Tang, Ying Tu & Haifeng Hu

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  1. Jun Yan
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  2. Li Ma
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  3. Mengyu Gan
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  4. Xiao Li
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  5. Zhitao Li
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  6. Jihai Tang
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  7. Ying Tu
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  8. Haifeng Hu
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Correspondence to Li Ma.

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Yan, J., Ma, L., Gan, M. et al. The effect of H2O2/Fe2+ catalytic oxidation system on the morphology, structure and properties of flake-like poly(2,3-dimethylaniline). Macromol. Res. 22, 853–858 (2014). https://doi.org/10.1007/s13233-014-2111-0

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  • DOI: https://doi.org/10.1007/s13233-014-2111-0

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