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Evaluating the anthropogenic impacts on groundwaters; a methodology based on the determination of natural background levels and threshold values

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Abstract

The present work investigates the long-term effects of human intervention on groundwaters based on the determination of natural background levels (NBLs) and threshold values (TVs) for groundwater electrical conductivity, chloride, ammonium, sulphates and nitrates. The methodology adopted is the one proposed in the 6th Framework European Project “BRIDGE”, which was applied with some adjustments in Rhodope area (Northern Greece). The study area was especially selected because it incorporates two distinct subareas: the northern one which can be safely considered as a pristine area, where NBLs for groundwaters were assessed from; the southern part which forms a typical Mediterranean region, intensively cultivated for the last 40 years. Groundwater TVs were determined considering two types of groundwater receptors: (a) groundwater ‘itself’ and (b) groundwater dependent lagoons in the coastal part of the study area. Results showed that groundwater quality is altered seriously from its natural background composition indicating how human activities have affected groundwater quality and showed that chemical status of groundwater has been seriously aggravated. The number and the spatial distribution of monitoring locations exceeding TVs revealed that chloride and nitrates are the most serious threats for groundwater in the study area.

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Abbreviations

NBL:

Natural background level

TV:

Threshold values

GWD:

EU Groundwater Directive

WFD:

EU Water Framework Directive

EC:

Electrical conductivity

References

  • Antonellini M, Mollema PN (2010) Impact of groundwater salinity on vegetation species richness in the coastal pine forests and wetlands of Ravenna, Italy. Ecol Eng 36:1201–1211. doi:10.1016/j.ecoleng.2009.12.007

    Article  Google Scholar 

  • BaSeLiNe (2004) Baseline quality in European aquifers: A basis for aquifer management. http://www.eugris.info/DisplayProject.asp?P=4163. Accessed 30 Nov 2010

  • BRIDGE (2009) Background criteria for the identification of groundwater thresholds. http://nfp-at.eionet.europa.eu/irc/eionet-circle/bridge/info/data/en/index.htm. Accessed 30 Nov 2010

  • Canadian Council of Ministers of the Environment (2003) Canadian water quality guidelines for the protection of aquatic life: nitrate ion. CCMI, Winnipeg. http://ceqg-rcqe.ccme.ca. Accessed 11 Feb 2011

  • Danielopol DL, Griebler C, Gunatilaka A, Notenboom J (2003) Present state and future prospects for groundwater ecosystems. Environ Conserv 30:104–130

    Article  Google Scholar 

  • Dimadis E, Gemitzi A, Karmis P (2001) Hydrogeological study of Rodopi’s district mountainous area, Greece. Institute of Geological and Mining Exploration, Greece

    Google Scholar 

  • Directive 2006/44/EC of the European Parliament and of the Council on the quality of fresh waters needing protection or improvement in order to support fish life OJ L 264, 25/9/2006, pp 20–31

  • Edmunds WM, Shand P (2008) Natural groundwater quality. Wiley-Blackwell, London

    Book  Google Scholar 

  • Edmunds WM, Cook JM, Darling WG, Kinniburgh DG, Miles DL, Bath AH, Morgan-Jones M, Andrews JN (1987) Baseline geochemical conditions in the chalk aquifer, Berkshire, UK: a basis for groundwater quality management. Appl Geochem 2:251–274

    Article  Google Scholar 

  • Edmunds WM, Shand P, Hart P, Ward RS (2003) The natural (baseline) quality of groundwater: a UK pilot study. Sci Tot Environ 310:25–35. doi:10.1016/S0048-9697(02)00620-4

    Article  Google Scholar 

  • European Commission (2009) Guidance on groundwater status and trend assessment, guidance document no 18. Technical Report 2009. ISBN 978-92-79-11374-1 European Communities, Luxembourg

  • European Commission (2010) Commission Staff Working Document accompanying the Report from the Commission in accordance with Article 3.7 of the Groundwater Directive 2006/118/EC on the establishment of groundwater threshold values Brussels, SEC(2010) 166 final

  • Gemitzi A, Stefanopoulos K (2011) Evaluation of the effects of climate and man intervention on ground waters and their dependent ecosystems using time series analysis. J Hydrol 403:130–140

    Article  Google Scholar 

  • Gomis-Yagues V, Boluda-Botella N, Ruiz-Bevia F (2000) Gypsum precipitation/dissolution as an explanation of the decrease of sulphate concentration during seawater intrusion. J Hydrol 228:48–55

    Article  Google Scholar 

  • Greek National Statistical Service (2001) Census data for 2001. http://www.statistics.gr. Accessed 10 Jan 2011

  • GWD (2006) Groundwater Directive 2006/118/CE, Directive of the European Parliament and of the Council on the protection of groundwater against pollution and deterioration, OJ L372, 27/12/2006, pp 19–31

  • Hart A, Müller D, Blum A, Hookey J, Kunkel R, Schleider A (2006) Preliminary methodology to derive environmental threshold values. In: Report to the EU project ‘‘BRIDGE’’ 2006, Deliverable D15. http://www.wfd-bridge.net. Accessed 10 Dec 2010

  • Hernandez-Garcıa ME, Custodio E (2004) Natural baseline quality of Madrid Tertiary Detrital Aquifer groundwater (Spain): a basis for aquifer management. Environ Geol 46:173–188

    Google Scholar 

  • Hinsby K, Condesso de Melo MT (2006) Application and evaluation of a proposed methodology for derivation of groundwater threshold values—a case study summary report. http://www.wfd-bridge.net. Accessed 10 Dec 2010

  • Hinsby K, Condesso de Melo MT, Dahl M (2008) European case studies supporting the derivation of natural background levels and groundwater threshold values for the protection of dependent ecosystems and human health. Sci Tot Environ 401:1–20

    Article  Google Scholar 

  • Hose GC (2005) Assessing the need for groundwater quality guidelines for pesticides using the species sensitivity distribution approach. Hum Ecol Risk Assess 11:951–966

    Article  Google Scholar 

  • Kallioras A, Pliakas F, Diamantis I (2006) Conceptual model of a coastal aquifer system in northern Greece and assessment of saline vulnerability due to seawater intrusion conditions. Environ Geol 51:349–361. doi:10.1007/s00254-006-0331-0

    Article  Google Scholar 

  • Kilias A, Falalakis G, Mountrakis D (1999) Cretaceous-Tertiary structures and kinematics of the Serbomacedonian metamorphic rocks and their relation to the exhumation of the Hellenic hinterland (Macedonia, Greece). Int J Earth Sci 88:513–531

    Article  Google Scholar 

  • Langmuir D (1997) Aqueous environmental chemistry. Prentice Hall, New Jersey, p 600

    Google Scholar 

  • Marandi A, Karro E (2008) Natural background levels and threshold values of monitored parameters in the Cambrian–Vendian groundwater body Estonia. Environ Geol 54:1217–1225. doi:10.1007/s00254-007-0904-6

    Article  Google Scholar 

  • Müller D, Blum A, Hart A, Hookey J, Kunkel R, Scheidleder A, Tomlin C, Wendland F (2006) Final proposal for a methodology to set up groundwater threshold values in Europe. In: Report to the EU project ‘‘BRIDGE’’ 2006, Deliverable D18. http://www.wfd-bridge.net. Accessed 10 Dec 2010

  • Preziosi E, Giuliano G, Vivona R (2010) Natural background levels and threshold values derivation for naturally As, V and F rich groundwater bodies: a methodological case study in Central Italy. Environ Earth Sci 61:885–897. doi:10.1007/s12665-009-0404-y

    Article  Google Scholar 

  • Rosca A, Rosu A, Vliegenthartf FJL, Schipper P (2008) Natural background values and threshold values required by the groundwater directive, applicable for Banat hydrographical area. EU Groundwater Policy Developments Conference, UNESCO, Paris, France, 13–15 Nov 2008

  • Stuyfzand PJ (1989) A new hydrochemical classification of water types. Regional characterization of water quality. In: Proceedings of the Baltimore Symposium, IAHS Publ. no. 182

  • Stuyfzand PJ (1993) Hydrochemistry and hydrology of the coastal dune area of the Western Netherlands. PhD, Free University of Amsterdam, published by Kiwa Ltd, Research and Consultancy, Nieuwegein, The Netherlands. ISBN 90-74741-01-0

  • Stuyfzand PJ (1999) Patterns in groundwater chemistry resulting from groundwater flow. Hydrol J 7:15–27

    Google Scholar 

  • Thorling L, Larsen CL, Hinsby K (2008) The challenge of deriving threshold values and background levels for groundwater in Denmark. EU Groundwater Policy Developments Conference, UNESCO, Paris, France, 13–15 Nov 2008

  • Venkatesan G, Swaminathan G (2009) Review of chloride and sulphate attenuation in groundwater nearby solid-water landfill sites. J Environ Eng Landsc Manag 17:Ia–Ig

    Google Scholar 

  • Walter T (2008) Determining natural background values with probability plots. EU Groundwater Policy Developments Conference, UNESCO, Paris, France, 13–15 Nov 2008

  • WFD (2000) Water Framework Directive, 2000/60/CE. Directive of the European Parliament and of the Council of 23 October 2000 establishing a framework for Community action in the field of water policy, OJ L327, 22 Dec 2000, pp 1–72

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Acknowledgments

This work is developed within the frames of the European FP7 project GENESIS (Groundwater and Dependent Ecosystems: New Scientific and Technical Basis for Assessing Climate Change and Land-use Impacts on Groundwater Systems). Grant agreement no.: 226536 – GENESIS CP-IP. Author acknowledges Berne N. Jansson, Project Director of Thracian Gold Mining S.A., for his comments on the manuscript and George Falalakis, Exploration Manager of Thracian Gold Mining S.A., for his fruitful discussions on the geology of the study area. Author also thanks Emilios Koutsiakis, agronomist at the Regional Unit of Rhodope, who provided detailed information concerning the land uses in Rhodope area. Author would also like to thank the anonymous reviewers for their constructive comments and suggestions.

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Gemitzi, A. Evaluating the anthropogenic impacts on groundwaters; a methodology based on the determination of natural background levels and threshold values. Environ Earth Sci 67, 2223–2237 (2012). https://doi.org/10.1007/s12665-012-1664-5

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