Abstract
In this study, the effect of annealing temperature and alumina particles on micro-hardness, corrosion, wear, and friction of Ni-P-Al2O3 composites coating is studied. The electroless nickel composite coating with various alumina particle content is deposited on a mild steel substrate. The corrosion behaviour and tribological behaviour (wear and friction) of the composite coated samples are investigated and compared with Ni-P coated samples. The micro-hardness, wear resistance, and corrosion resistance of the composite coating improved significantly after heat treatment (400 °C) and in the presence of alumina particles. The composite coating deposited with alumina particle concentration of 10 g/L in an electroless bath and heat treated at 400 °C shows excellent results compared to Ni-P, as-deposited Ni-P-Al2O3 coating and coatings heat treated at different annealing temperature (200 °C, 300 °C, and 500 °C). Microstructure changes and composition of the composite coatings due to incorporation of alumina particles and heat treatment are studied with the help of SEM (scanning electron microscopy), EDX (energy dispersive X-ray analysis and XRD (X-ray diffraction analysis).
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References
Sahoo P, Das SK (2011) Tribology of electroless nickel coating – A review. Mater Des 32:1760–1775
Sudagar J, Lian J, Sha W (2013) Electroless nickel, alloy, composite, and nano coatings – A critical review. J Alloys Compd 571:183–204
Gadhari P, Sahoo P (2016) Electroless nickel-phosphorus composite coatings – A review, International Journal of Manufacturing. Mater Mech Eng 6(1):14–50
Gadhari P, Sahoo P (2015) Improvement in tribological performance of Ni-P-TiO2 composite coatings using Taguchi technique with grey relational analysis, Indian Journal of Materials Science, vol 2015, Article ID 104187, 1–10
Gadhari P, Sahoo P (2015) Effect of process parameters on corrosion resistance of Ni-P-Al2O3 composite coatings using electrochemical impedance spectroscopy. Port Electrochim Acta 33(1):49–68
Apachitei I, Tichelaar FD, Duszczyk J, Katgerman L (2002) The effect of heat treatment on the structure and abrasive wear resistance of autocatalytic Ni-P and Ni-P-SiC coatings. Surf Coat Technol 149(2):263–278
Franco M, Sha W, Malinov S, Rajendran R (2013) Phase composition, microstructure and microhardness of electroless nickel composite coating co-deposited with SiC on cast aluminum LM24 alloy substrate. Surf Coat Technol 235:755–763
Araghi A, Paydar MH (2010) Electroless deposition of Ni-P-B4C composite coating on AZ91D magnesium alloy and investigation on its wear and corrosion resistance. Mater Des 31 (6):3095– 3099
Stankiewicz A, Masalski J, Szczygiel B (2012) Impedance spectroscopy studies of electroless Ni-P matrix, Ni-W-P, Ni-P-ZrO2, and Ni-W-P-ZrO2 coating exposed to 3.5 % NaCl solution. Mater Corros 63(10):908–913
Jappes JW, Ramamoorthy B, Nair PK (2009) Novel approaches on the study of wear performance of electroless Ni-P/diamond composite deposits. J Mater Process Technol 209(2):1004–1010
Leon OA, Staia MH, Hintermann HE (2003) High temperature wear of an electroless Ni-P-BN(h) composite coating. Surf Coat Technol 163:578–584
Sivandipoor I, Ashrafizadeh F (2012) Synthesis and tribological behavior of electroless Ni-P-WS2 composite coatings. Appl Surf Sci 263:314–319
Mafi IR, Dehghanian C (2011) Comparison of the coating properties and corrosion rates in electroless Ni-P/PTFE composites prepared by different types of surfactants. Appl Surf Sci 257(20):8653–8658
Mohammadi M, Ghorbani M, Azizi A (2010) Effect of specimen orientation heat treatment on electroless Ni-P-PTFE-MoS2 composite coatings. J. Coat. Technol. Res. 7(6):697–702
Apachitei I, Tichelaar FD, Duszczyk J, Katgerman L (2001) Solid–state reactions in low phosphorus autocatalytic NiPSiC coatings. Surf Coat Technol 148:284295
Leon OA, Staia MH, Hintermann HE (2005) Wear mechanism of Ni-P-BN (h) composite autocatalytic coatings. Surf Coat Technol 200:1825–1829
Bozzini B, Boniardi M, Fanigliulo A, Bogani F (2001) Tribological properties of electroless Ni-P/diamond composite films. Mater Res Bullet 36:1889–1902
Xu H, Yang Z, Li MK, Shi YL, Huang Y, Li HL (2005) Synthesis and properties of electroless Ni-P-Nanometer Diamond composite coatings. Surf Coat Technol 191:161–165
Grosjean A, Rezrazi m., Takadoum J, Bercot P (2001) Hardness, friction and wear characteristics of nickel-SiC electroless composite deposits. Surf Coat Technol 137:92–96
Chen W, Gao W, He Y (2010) A novel electroless plating of Ni-P-TiO2 nano-composite coatings. Surf Coat Technol 204:2493–2498
Mohammadi M, Ghorbani M (2011) Wear and corrosion properties of electroless nickel composite coatings with PTFE and/or MoS2 particles. J Coat Technol Res 8(4):527–533
Zarebidaki A, Allahkaram SR (2012) Effect of heat treatment on the properties of electroless NiPcarbon nano-tube composite coatings. Micro Nano Lett 7(1):9094
Praveen BM, Venkatesha TV, Naik YA, Prashantha K (2007) Corrosion studies of carbon nanotubesZn composite coating. Surf Coat Technol 201:58365842
Malfatti CF, Ferreira JZ, Santos CB, Souza BV, Fallavena EP, Vaillant S, Bonino JP (2005) NiP/SiC composite coatings: the effects of particles on the electrochemical behaviour. Corros Sci 47:567–580
Zarebidaki A, Allahkaram SR (2011) Corrosion assessment of electroless nickelphosphorous/nano–silicon carbide composite coatings. Micro Nano Lett 6(11):937940
Xu H, Yang Z, Li MK, Shi YL, Huang Y, Li HL (2005) Synthesis and properties of electroless Ni-P-Nanometer Diamond composite coatings. Surf Coat Technol 191:161–165
Liu D, Yan Y, Lee K, Yu J (2009) Effect of surfactant on the alumina dispersion and corrosion behavior of electroless NiPAl2O3 composite coatings. Mater Corros 60(9):690694
Allahkaram SR, Zoughi M, Rabizadeh T (2010) Studying the influence of nano Al2O3 particles on morphology and corrosion improvement of Ni–9 %P electroless coatings. Micro Nano Lett 5(5):262–265
Lee CK (2012) Comparative corrosion resistance of electroless Ni–P/nanoTiO2 and NiP/nanoCNT composite coatings on 5083 aluminum alloy. Int J Electrochem Sci 7:1294112954
Valova E, Georgiev I, Armyanov S, Delplancke JL, Tachev D, Tsacheva T. s., Dille J (2001) Incorporation of zinc in electroless deposited nickel-phosphorus alloys: a comparative study of Ni-P and Ni-Zn-P coatings deposition, structure, and composition. J Electrochem Soc 148:C266–C273
Ranganatha S, Venkatesha TV, Vathsala K (2010) Development of electroless Ni-Zn-P/nano-TiO2 composite coatings and their properties. Appl Surf Sci 256:7377–7383
Balaraju JN, Kalavati Rajam K. S. (2010) Electroless ternary Ni-W-P alloys containing micron size Al2O3 particles. Surf Coat Technol 205:575–581
Vojtech D (2009) Properties of hard Ni-P-Al2O3 and Ni-P-SiC coatings on al-based casting alloys. Mater Manuf Process 24:754–757
Leon C, Gracia-Ochoa E, Gracia-Guerra J, Gonzalez-Sanchez J (2010) Annealing temperature effect on corrosion parameters of autocatalytically produced Ni-P and Ni-P-Al2O3 coatings in artificial seawater. Surf Coat Technol 205:2425–2431
Franco M, Sha W, Malinov S, Liu H (2014) Micro-scale wear characteristics of electroless Ni-P/SiC composite coating under two different sliding conditions. Wear 317:254–264
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Gadhari, P., Sahoo, P. Effect of Annealing Temperature and Alumina Particles on Mechanical and Tribological Properties of Ni-P-Al2O3 Composite Coatings. Silicon 9, 761–774 (2017). https://doi.org/10.1007/s12633-016-9452-6
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DOI: https://doi.org/10.1007/s12633-016-9452-6