Skip to main content
Log in

Effect of Annealing Temperature and Alumina Particles on Mechanical and Tribological Properties of Ni-P-Al2O3 Composite Coatings

  • Original Paper
  • Published:
Silicon Aims and scope Submit manuscript

Abstract

In this study, the effect of annealing temperature and alumina particles on micro-hardness, corrosion, wear, and friction of Ni-P-Al2O3 composites coating is studied. The electroless nickel composite coating with various alumina particle content is deposited on a mild steel substrate. The corrosion behaviour and tribological behaviour (wear and friction) of the composite coated samples are investigated and compared with Ni-P coated samples. The micro-hardness, wear resistance, and corrosion resistance of the composite coating improved significantly after heat treatment (400 °C) and in the presence of alumina particles. The composite coating deposited with alumina particle concentration of 10 g/L in an electroless bath and heat treated at 400 °C shows excellent results compared to Ni-P, as-deposited Ni-P-Al2O3 coating and coatings heat treated at different annealing temperature (200 °C, 300 °C, and 500 °C). Microstructure changes and composition of the composite coatings due to incorporation of alumina particles and heat treatment are studied with the help of SEM (scanning electron microscopy), EDX (energy dispersive X-ray analysis and XRD (X-ray diffraction analysis).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Sahoo P, Das SK (2011) Tribology of electroless nickel coating – A review. Mater Des 32:1760–1775

    Article  CAS  Google Scholar 

  2. Sudagar J, Lian J, Sha W (2013) Electroless nickel, alloy, composite, and nano coatings – A critical review. J Alloys Compd 571:183–204

    Article  CAS  Google Scholar 

  3. Gadhari P, Sahoo P (2016) Electroless nickel-phosphorus composite coatings – A review, International Journal of Manufacturing. Mater Mech Eng 6(1):14–50

    Google Scholar 

  4. Gadhari P, Sahoo P (2015) Improvement in tribological performance of Ni-P-TiO2 composite coatings using Taguchi technique with grey relational analysis, Indian Journal of Materials Science, vol 2015, Article ID 104187, 1–10

  5. Gadhari P, Sahoo P (2015) Effect of process parameters on corrosion resistance of Ni-P-Al2O3 composite coatings using electrochemical impedance spectroscopy. Port Electrochim Acta 33(1):49–68

    Article  CAS  Google Scholar 

  6. Apachitei I, Tichelaar FD, Duszczyk J, Katgerman L (2002) The effect of heat treatment on the structure and abrasive wear resistance of autocatalytic Ni-P and Ni-P-SiC coatings. Surf Coat Technol 149(2):263–278

    Article  CAS  Google Scholar 

  7. Franco M, Sha W, Malinov S, Rajendran R (2013) Phase composition, microstructure and microhardness of electroless nickel composite coating co-deposited with SiC on cast aluminum LM24 alloy substrate. Surf Coat Technol 235:755–763

    Article  CAS  Google Scholar 

  8. Araghi A, Paydar MH (2010) Electroless deposition of Ni-P-B4C composite coating on AZ91D magnesium alloy and investigation on its wear and corrosion resistance. Mater Des 31 (6):3095– 3099

    Article  CAS  Google Scholar 

  9. Stankiewicz A, Masalski J, Szczygiel B (2012) Impedance spectroscopy studies of electroless Ni-P matrix, Ni-W-P, Ni-P-ZrO2, and Ni-W-P-ZrO2 coating exposed to 3.5 % NaCl solution. Mater Corros 63(10):908–913

    Google Scholar 

  10. Jappes JW, Ramamoorthy B, Nair PK (2009) Novel approaches on the study of wear performance of electroless Ni-P/diamond composite deposits. J Mater Process Technol 209(2):1004–1010

    Article  Google Scholar 

  11. Leon OA, Staia MH, Hintermann HE (2003) High temperature wear of an electroless Ni-P-BN(h) composite coating. Surf Coat Technol 163:578–584

    Article  Google Scholar 

  12. Sivandipoor I, Ashrafizadeh F (2012) Synthesis and tribological behavior of electroless Ni-P-WS2 composite coatings. Appl Surf Sci 263:314–319

    Article  CAS  Google Scholar 

  13. Mafi IR, Dehghanian C (2011) Comparison of the coating properties and corrosion rates in electroless Ni-P/PTFE composites prepared by different types of surfactants. Appl Surf Sci 257(20):8653–8658

    Article  CAS  Google Scholar 

  14. Mohammadi M, Ghorbani M, Azizi A (2010) Effect of specimen orientation heat treatment on electroless Ni-P-PTFE-MoS2 composite coatings. J. Coat. Technol. Res. 7(6):697–702

    Article  CAS  Google Scholar 

  15. Apachitei I, Tichelaar FD, Duszczyk J, Katgerman L (2001) Solid–state reactions in low phosphorus autocatalytic NiPSiC coatings. Surf Coat Technol 148:284295

    Article  Google Scholar 

  16. Leon OA, Staia MH, Hintermann HE (2005) Wear mechanism of Ni-P-BN (h) composite autocatalytic coatings. Surf Coat Technol 200:1825–1829

    Article  CAS  Google Scholar 

  17. Bozzini B, Boniardi M, Fanigliulo A, Bogani F (2001) Tribological properties of electroless Ni-P/diamond composite films. Mater Res Bullet 36:1889–1902

    Article  CAS  Google Scholar 

  18. Xu H, Yang Z, Li MK, Shi YL, Huang Y, Li HL (2005) Synthesis and properties of electroless Ni-P-Nanometer Diamond composite coatings. Surf Coat Technol 191:161–165

    Article  CAS  Google Scholar 

  19. Grosjean A, Rezrazi m., Takadoum J, Bercot P (2001) Hardness, friction and wear characteristics of nickel-SiC electroless composite deposits. Surf Coat Technol 137:92–96

    Article  CAS  Google Scholar 

  20. Chen W, Gao W, He Y (2010) A novel electroless plating of Ni-P-TiO2 nano-composite coatings. Surf Coat Technol 204:2493–2498

    Article  CAS  Google Scholar 

  21. Mohammadi M, Ghorbani M (2011) Wear and corrosion properties of electroless nickel composite coatings with PTFE and/or MoS2 particles. J Coat Technol Res 8(4):527–533

    Article  CAS  Google Scholar 

  22. Zarebidaki A, Allahkaram SR (2012) Effect of heat treatment on the properties of electroless NiPcarbon nano-tube composite coatings. Micro Nano Lett 7(1):9094

    Article  Google Scholar 

  23. Praveen BM, Venkatesha TV, Naik YA, Prashantha K (2007) Corrosion studies of carbon nanotubesZn composite coating. Surf Coat Technol 201:58365842

    Article  Google Scholar 

  24. Malfatti CF, Ferreira JZ, Santos CB, Souza BV, Fallavena EP, Vaillant S, Bonino JP (2005) NiP/SiC composite coatings: the effects of particles on the electrochemical behaviour. Corros Sci 47:567–580

    Article  CAS  Google Scholar 

  25. Zarebidaki A, Allahkaram SR (2011) Corrosion assessment of electroless nickelphosphorous/nano–silicon carbide composite coatings. Micro Nano Lett 6(11):937940

    Article  Google Scholar 

  26. Xu H, Yang Z, Li MK, Shi YL, Huang Y, Li HL (2005) Synthesis and properties of electroless Ni-P-Nanometer Diamond composite coatings. Surf Coat Technol 191:161–165

    Article  CAS  Google Scholar 

  27. Liu D, Yan Y, Lee K, Yu J (2009) Effect of surfactant on the alumina dispersion and corrosion behavior of electroless NiPAl2O3 composite coatings. Mater Corros 60(9):690694

    Article  Google Scholar 

  28. Allahkaram SR, Zoughi M, Rabizadeh T (2010) Studying the influence of nano Al2O3 particles on morphology and corrosion improvement of Ni–9 %P electroless coatings. Micro Nano Lett 5(5):262–265

    Article  CAS  Google Scholar 

  29. Lee CK (2012) Comparative corrosion resistance of electroless Ni–P/nanoTiO2 and NiP/nanoCNT composite coatings on 5083 aluminum alloy. Int J Electrochem Sci 7:1294112954

    Google Scholar 

  30. Valova E, Georgiev I, Armyanov S, Delplancke JL, Tachev D, Tsacheva T. s., Dille J (2001) Incorporation of zinc in electroless deposited nickel-phosphorus alloys: a comparative study of Ni-P and Ni-Zn-P coatings deposition, structure, and composition. J Electrochem Soc 148:C266–C273

    Article  CAS  Google Scholar 

  31. Ranganatha S, Venkatesha TV, Vathsala K (2010) Development of electroless Ni-Zn-P/nano-TiO2 composite coatings and their properties. Appl Surf Sci 256:7377–7383

    Article  CAS  Google Scholar 

  32. Balaraju JN, Kalavati Rajam K. S. (2010) Electroless ternary Ni-W-P alloys containing micron size Al2O3 particles. Surf Coat Technol 205:575–581

    Article  CAS  Google Scholar 

  33. Vojtech D (2009) Properties of hard Ni-P-Al2O3 and Ni-P-SiC coatings on al-based casting alloys. Mater Manuf Process 24:754–757

    Article  CAS  Google Scholar 

  34. Leon C, Gracia-Ochoa E, Gracia-Guerra J, Gonzalez-Sanchez J (2010) Annealing temperature effect on corrosion parameters of autocatalytically produced Ni-P and Ni-P-Al2O3 coatings in artificial seawater. Surf Coat Technol 205:2425–2431

    Article  CAS  Google Scholar 

  35. Franco M, Sha W, Malinov S, Liu H (2014) Micro-scale wear characteristics of electroless Ni-P/SiC composite coating under two different sliding conditions. Wear 317:254–264

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Prasanta Sahoo.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gadhari, P., Sahoo, P. Effect of Annealing Temperature and Alumina Particles on Mechanical and Tribological Properties of Ni-P-Al2O3 Composite Coatings. Silicon 9, 761–774 (2017). https://doi.org/10.1007/s12633-016-9452-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12633-016-9452-6

Keywords

Navigation