Skip to main content
Log in

The Influence of Heat Treatment and Process Parameters Optimization on Hardness and Corrosion Properties of Laser Alloyed X12CrNiMo Steel

  • Original Paper
  • Published:
Silicon Aims and scope Submit manuscript

Abstract

Martensitic stainless steels are used in the production of steam turbine blades but their application is limited due to low hardness and poor corrosion resistance. Laser surface alloying and heat treatment of X12CrNiMo Martensitic stainless steel was conducted with the aim of enhancing hardness and corrosion properties. A Rofin Sinar Continuous Wave Nd: YAG solid-state laser was used to alloy the specimens. The electrochemical and hardness properties were studied using potentiodynamic polarization technique and Vickers micro hardness tester. The microstructures of the as-received, post-heated and pre-heated specimens were investigated by a Scanning Electron Microscope (SEM) and Optical Micrograph (OM) respectively. From the experimental results, the post-heated specimens exhibited the highest hardness property as compared to all other specimens. There was also significant improvement in the corrosion resistance of the post heated specimen compared to all other specimens and the substrate as evidenced by higher polarization resistance and lower corrosion rates. From the analysis of grey relational grade model, the significant laser processing parameters were identified. The results showed the influence of laser power and scanning speed on the corrosion rate, hardness and alloyed depth. The predicted results were found to be in good agreement with the experimental results.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Mahmoudi B, Torkamany MJ, Sabour AR, Sabbaghzade J (2010) Laser surface hardening of AISI 420 stainless steel treated by pulse N: YAG laser. Mater Des 31:2553–2560

    Article  CAS  Google Scholar 

  2. Thamizhmanii S, Bin OB, Saparudin S, Hassan S (2008) Surface roughness analyses of hard martensitic stainless steel by turning. Journal of Achievements in Materials and Manufacturing Engineering 26:2

    Google Scholar 

  3. Yun-Tao X, Dao-Xin L, Dong H (2008) Improvement of corrosion and wear resistances of AISI 420 martensitic stainless steel using plasma nitriding at low temperature. Surf Coat Technol 202:2577–2583

    Article  Google Scholar 

  4. Vamsi C, Mohan K, Prakash S (2004) Surface modification of martensitic stainless using metal working CO 2 laser Paper presented at the International Symposium of Research Students on Materials Science and Engineering

  5. Calliari I, Zanesco M, Dabala M, Brunelli K, Ramous E (2008) Investigation of microstructure and properties of a Ni-Mo martensitic stainless steel. Mater Des 29:246–250

    Article  CAS  Google Scholar 

  6. Brytan Z, Bonek M, Dobrzanski LA (2010) Microstructure and properties of Laser surface alloyed PM austenitic stainless steels. Journal of Achievements in Materials and Manufacturing Engineering 40(1):70-79

    Google Scholar 

  7. Thawari G, Sundararajan G, Joshi SV (2003) Laser surface alloying of medium carbon steel with SiCp. Thin Solid Films 423:41–53

    Article  CAS  Google Scholar 

  8. Adebiyi DI, Popoola API, Ogunnyi IO (2010) Hardness and Microstructure of X12CrNiMo Martensitic Stainless Steel Laser Alloyed with Titanium Carbide. In: Proceedings of South African institute of physics conference, held in pretoria, South Africa on the 26 th-30 th

  9. Ayers JD, Tucker TR (1980) Particulate-TiC-hardened steel surfaces by laser melt injection. Thin Solid Films 73(3):201- 207

    Article  CAS  Google Scholar 

  10. Marsdon C, West DRF, Steen WM (1986) Surface treatment of metals, Dordrecht The Netherlands: Martinus Nijhoff Publishers

  11. Kim TH, Kim BC (1992) Chromium carbide laser-beam surface alloying treatment on stainless steel. J Mater Sci 27(11):2967–2973

    Article  CAS  Google Scholar 

  12. Adebiyi DI, Fedotova T, Pityana SL, Popoola API (2011) Improved hardness of laser alloyed X12CrNiMo martensitic stainless steel. International Journal of the Physical Sciences 6(11):3336–3346

    CAS  Google Scholar 

  13. Rieker C, Morris DG, Steffen J (1989) Formation of hard microcrystalline layers on stainless steel by laser alloying. Mater Sci Technol 5:590–594

    Article  CAS  Google Scholar 

  14. Lo KH, Cheng FT, Kwok CT, Man HC (2003) Improvement of cavitation erosion resistance of AISI 316 stainless steel by laser surface alloying using fine WC powder. Surf Coat Technol 165:258–267

    Article  CAS  Google Scholar 

  15. Popoola API, Ochonogor OF, Abdulwahab M, Pityana SL, Meacock C (2012) Microhardness and wear behaviour of surface modified Ti6Al4V/Zr-TiC metal matrix composite for advanced material. J Optoelectron Adv Mater 14(11-12):991– 997

    CAS  Google Scholar 

  16. Nasery Isfahany A, Saghafian H, Borhani G (2011) Effects of Heat Treatment on Mechanical Properties and Corrosion Behavior of AISI 420 Martensitic stainless steel. J Alloys Compd 509:3931–3936

    Article  Google Scholar 

  17. Kwok CT, Lo KH, Cheng FT, Man HC (2000) Cavitation erosion and pitting corrosion behaviours of Laser-Melted martensitic stainless steel UNS s42000. Surf Coat Technol 126:238–255

    Article  CAS  Google Scholar 

  18. Rajasekhar A, Madhusudhan Reddy G, Mohandas T, Murti VSR (2009) Influence of Austenitizing temperature on Microstructure and Mechanical Properties of AISI 431 Martensitic stainless steel Electron Beam Welds. Mater Des 30:1612–1624

    Article  CAS  Google Scholar 

  19. Lui Y, Ye D, Yong Q, Su J, Zhao K, Jiang W (2011) Effect of Heat Treatment on Microstructure and Property of Cr13 Super Martensitic stainless steel. Journal of Steel Research International 18:60–65

    Google Scholar 

  20. Candelaria AF, Pinedo CE (2003) Influence of the heat treatment on the corrosion resistance of the martensitic stainless steel type AISI 420. J Mater Sci 22:1151–1153

    CAS  Google Scholar 

  21. Popoola API, Adebiyi DI (2011) Three body abrasive wear of X12CrNiMo martensitic stainless steel laser alloyed with TiC. Sci Res Essays 6(29):6104–6115

    CAS  Google Scholar 

  22. Datta S, Bandyopadhyay A, Pal PK (2008) Grey-based Taguchi method for optimization of bead geometry in submerged arc bead-on-plate welding. Int J Adv Manuf Technol 39:1136–1143

    Article  Google Scholar 

  23. Jenabali Jahromi SA, Khajeh A, Mahmoudi B (2012) Effect of Different Pre-heat Treatment Processes on the Hardness of AISI 410 Martensitic stainless steel surface-treated using Pulsed Neodymium-doped yttrium aluminium garnet laser. Mater Des 34:857–862

    Article  CAS  Google Scholar 

  24. Samal PK, Walko JC, Pannell JD (2009) Processing and properties of PM 440C stainless steel, vol 15935. North American Hoganas, Hollsopple PA, pp 1–10

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. P. I. Popoola.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

I. Popoola, A.P., Fatoba, O.S., Popoola, O.M. et al. The Influence of Heat Treatment and Process Parameters Optimization on Hardness and Corrosion Properties of Laser Alloyed X12CrNiMo Steel. Silicon 8, 579–589 (2016). https://doi.org/10.1007/s12633-016-9434-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12633-016-9434-8

Keywords

Navigation